Effect of photoinitiator concentration on hygroscopic stability of UV cured precision replicated composite optics.

Replicated composite optics is a promising technique to fabricate high-quality mirrors with reduced weight and processing time compared to conventional glass mirrors; however, the optical layer is organic and susceptible to environmentally-induced dimensional changes, specifically to moisture exposures. Generally, to enhance polymer stability, thermal curing is necessary to maximize the cure state. Because replications are bonded, thermal exposures generate residual stresses that degrade optical quality.