Publications by authors named "Gayathri Rangasamy"

This study investigates the removal of ibuprofen and diclofenac from aqueous media via a fully pressurized dissolved air flotation system, enhanced by fenugreek-derived saponin, a plant-based biosurfactant. The use of fenugreek saponin in flotation processes distinguishes this work from previous studies as it offers an ecofriendly and efficient alternative to chemical surfactants. The biosurfactant's surface-active properties were confirmed through FT-IR, UV-vis spectroscopy identified key functional groups and structural characteristics of the saponin, NMR provided molecular insights into its bioactive components, and surface tension analyses demonstrated its ability to reduce interfacial tension, indicating effective surfactant behavior.

View Article and Find Full Text PDF

Degradation of tartrazine dye (TZD) was performed in this study using sulfate radicals (SO) generated from the activated sodium persulfate (SPS) using FeO@PDA nanoparticles (NPs). The NPs were characterized by Fourier transform infrared (FTIR), vibrating sample magnetometer (VSM), X-ray diffraction (XRD), high-resolution scanning electron microscopy (HR-SEM), X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (HRTEM), and energy-dispersive X-ray spectroscopy (EDX). The average particle size of the NPs was 17.

View Article and Find Full Text PDF

In the current research work, an advanced oxidation process was applied to the degradation of Remazol brilliant blue dye (RBBD) using a sulfate radical. FeO@PDA nanoparticles were synthesized using coprecipitation and self-polymerization techniques. Nanoparticle formation was confirmed by XRD, FTIR, FESEM-EDX, VSM, and XPS analyses.

View Article and Find Full Text PDF

The development of biocompatible adsorbents is vital for environmental remediation to control and reduce pollution and waste accumulation in ecosystems. Biocompatible hydrogels represent an innovative class of materials that are primarily composed of polymer chain units forming their structural framework. They have a high affinity for water molecules.

View Article and Find Full Text PDF
Article Synopsis
  • - The study investigated bifunctional electrocatalysts for water splitting, focusing on nonprecious materials to enhance sustainable energy solutions.
  • - Researchers developed rGO/MnO/MoS nanohybrids that improved water splitting efficiency by increasing surface area and electroactive sites.
  • - These nanohybrids showed impressive catalytic performance for both hydrogen and oxygen production with low energy requirements, highlighting their potential for renewable energy applications.
View Article and Find Full Text PDF

This study introduces a new biosorbent derived from Delonix regia bark-activated carbon to efficiently remove Chromium Cr(VI) metal ions from aqueous systems. The biosorbent was synthesized from the bark powder of the plant species and chemically activated with phosphoric acid. The biosorbent was characterized using FTIR, SEM, and BET to determine its functional properties and structural morphology.

View Article and Find Full Text PDF

As an effort to tackle some of the most pressing ecological issues we are currently experiencing, there has been an increasing interest in employing biomass-derived char products in various disciplines. Thermal combustion of biomass results in biochar production, which is a remarkably rich source of carbon. Not only does the biochar obtained by the thermochemical breakdown of biomass lower the quantity of carbon released into the environment, but it also serves as an eco-friendly substitute for activated carbon (AC) and further carbon-containing products.

View Article and Find Full Text PDF

Polyaromatic hydrocarbons (PAHs) are the most persistent compounds that get contaminated in the soil and water. Nearly 16 PAHs was considered to be a very toxic according US protection Agency. Though its concentration level is low in the environments but the effects due to it, is enormous.

View Article and Find Full Text PDF
Article Synopsis
  • Measuring the concentration of organochlorine pesticides (OCPs) is crucial because they can harm human health and contaminate the environment and food supply.
  • Researchers developed a fluorescent blue emissive-carbon dot (B-CD) that can effectively detect OCPs in real samples, showing high sensitivity and specific binding to different types of OCPs.
  • The fluorescence method demonstrated low detection limits for various OCPs, making it a promising and efficient tool for monitoring pesticide residues in water and agricultural products.
View Article and Find Full Text PDF

Pollution is a global menace that poses harmful effects on all the living ecosystems and to the Earth. As years pass by, the available and the looming rate of pollutants increases at a faster rate. Although many treatments and processing strategies are waged for treating such pollutants, the by-products and the wastes or drain off generated by these treatments further engages in the emission of hazardous waste.

View Article and Find Full Text PDF

Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure.

View Article and Find Full Text PDF

The food packaging industries are facing the challenge of food waste generation. This can be addressed through the use of edible coating materials. These coatings aid in extending the shelf life of food products, reducing waste.

View Article and Find Full Text PDF

The persistence of organic/inorganic pollutants in the water has become a serious environmental issue. Among the different pollutants, dyes and heavy metal pollution in waterways are viewed as a global ecological problem that can have an impact on humans, plants, and animals. The necessity to develop a sustainable and environmentally acceptable approach to remove these toxic contaminants from the ecosystem has been raised.

View Article and Find Full Text PDF

Biohydrogen is an economical fuel which has enormous promise as an alternative energy source. The synthesis of biohydrogen can be done more affordably and sustainably using microalgae. For the generation of biohydrogen and the treatment of wastewater, microalgae derived from effluent have been showing very impressive outcomes.

View Article and Find Full Text PDF

The electrochemical degradation of alizarin red dye was studied using bismuth oxyhalide attached to bismuth vanadate nanocomposite synthesized via a simple solvothermal method. The electrochemical degradation of alizarin red dye was treated at current densities of 3 and 5 mA cm for 30 min under different supporting electrolyte mediums (NaCl and KCl). Also, the electrochemical degradation of BiOBr/BiVO electrode shows higher degradation percentages of 97 and 99 for NaCl and KCl electrolyte solutions, which are higher degradation percentages than pure BiVO electrode (88 and 91 for NaCl and KCl).

View Article and Find Full Text PDF

The environment worldwide has been contaminated by toxic pollutants and chemicals through anthropogenic activities, industrial growth, and urbanization. Microbial remediation is seen to be superior compared to conventional remediation due to its low cost, selectivity towards particular metal ions, and high efficiency. One key strategy in enhancing microbial remediation is employing an immobilization technique with biochar as a carrier.

View Article and Find Full Text PDF

In recent periods, a broad assortment of continual organic contaminants has been released into our natural water resources. Indeed, it is exceedingly poisonous and perilous to living things; thus, the elimination of these organic pollutants before release into the water bodies is vital. A variety of techniques have been utilized to remove these organic pollutants with advanced oxidation photocatalytic methods with zinc oxide (ZnO) nanoparticles being commonly used as a capable catalyst for contaminated water treatment.

View Article and Find Full Text PDF

Organochlorine pesticides (OCPs) have been used in agriculture, increasing crop yields and representing a serious and persistent global contaminant that is harmful to the environment and human health. OCPs are typically bioaccumulative and persistent chemicals that can spread over long distances. The challenge is to reduce the impacts caused by OCPs, which can be achieved by treating OCPs in an appropriate soil and water environment.

View Article and Find Full Text PDF

A co-precipitation technique has been used to prepare Bismuth tungstate nanoparticles (BiWO) for electrochemical capacitors and electrochemical sensing of Ascorbic acid (AA). Using a scanning rate of 10 mV s , the electrode was performed as the pseudocapacitance behavior and the specific capacitance to be up to 677 Fg at 1 A/g. BiWO versus Glassy carbon electrode (GCE) was also used to study the behavior of the BiWO modified electrodes in detecting ascorbic acid.

View Article and Find Full Text PDF

Synthesis and characterization of highly active cross-linked laccase aggregates (CLLAs) were performed and evaluated for removal of pentachlorophenol and phenanthrene from lignocellulosic biorefinery wastewater. Laccase from Tramates versicolor MTCC 138 was insolubilized as CLLAs via precipitation with 70% ammonium sulphate and simultaneous cross-linking with 5 mM glutaraldehyde to obtain activity recovery of 89.1%.

View Article and Find Full Text PDF
Article Synopsis
  • Decarbonization is increasingly vital due to growing energy needs and declining oil supplies, and biotechnology offers a cost-effective way to reduce carbon emissions.
  • Bioenergy generation stands out as an eco-friendly method for addressing climate change in the energy sector and is expected to significantly lower global carbon output.
  • The review emphasizes innovative biotechnological strategies, the role of engineered microbes in CO mitigation, and highlights the production of biohydrogen and biomethane through anaerobic digestion, while discussing the potential for creating various bioproducts from CO conversions.
View Article and Find Full Text PDF

Heavy metals, dyes and pharmaceutical pollutants in water environment are considered as serious threat to the human and animal health globally. Rapid development of industrialization and agricultural activities are the major source for eliminating the toxic pollutants into the aquatic environment. Several conventional treatment methods have been suggested for the removal of emerging contaminants from wastewater.

View Article and Find Full Text PDF

The progress of versatile chemicals and bio-based fuels using renewable biomass has gained ample importance. Furfural and 5-hydroxymethylfurfural are biomass-derived compounds that serve as the cornerstone for high-value chemicals and have a myriad of industrial applications. Despite the significant research into several chemical processes for furanic platform chemicals conversion, the harsh reaction conditions and toxic by-products render their biological conversion an ideal alternative strategy.

View Article and Find Full Text PDF

This study focuses on using Casuarina equisetifolia biomass for pilot-scale glucose oxidase production from Aspergillus niger and its application in the removal of trace organic contaminants (TrOCs) from municipal wastewater through the bio-Fenton oxidation. The cost of glucose oxidase was 0.005 $/U, including the optimum production parameters, 10% biomass, 7% sucrose, 1% peptone, and 3% CaCO at 96 h with an enzyme activity of 670 U/mL.

View Article and Find Full Text PDF

Neurotoxic pesticides are a group of chemicals that pose a severe threat to both human health and the environment. These molecules are also known to accumulate in the food chain and persist in the environment, which can lead to long-term exposure and adverse effects on non-target organisms. The detrimental effects of these pesticides on neurotransmitter levels and function can lead to a range of neurological and behavioral symptoms, which are closely associated with neurodegenerative diseases.

View Article and Find Full Text PDF