Oil and gas exploitation introduces toxic contaminants such as hydrocarbons and heavy metals to the surrounding sediment, resulting in deleterious impacts on marine benthic communities. This study combines benthic monitoring data over a 30-year period in the North Sea with dietary information on >1400 taxa to quantify the effects of active oil and gas platforms on benthic food webs using a multiple before-after control-impact experiment. Contamination from oil and gas platforms caused declines in benthic food web complexity, community abundance, and biodiversity.
View Article and Find Full Text PDFMetabolism, the biological processing of energy and materials, scales predictably with temperature and body size. Temperature effects on metabolism are normally studied via acute exposures, which overlooks the capacity for organisms to moderate their metabolism following chronic exposure to warming. Here, we conduct respirometry assays in situ and after transplanting salmonid fish among different streams to disentangle the effects of chronic and acute thermal exposure.
View Article and Find Full Text PDFThis study evaluated the effects of three commercial dispersants (Finasol OSR 52, Slickgone NS, Superdispersant 25) and three biosurfactants (rhamnolipid, trehalolipid, sophorolipid) in crude-oil seawater microcosms. We analysed the crucial early bacterial response (1 and 3 days). In contrast, most analyses miss this key period and instead focus on later time points after oil and dispersant addition.
View Article and Find Full Text PDFIn September 2017 the Agia Zoni II sank in the Saronic Gulf, Greece, releasing approximately 500 tonnes of heavy fuel oil, contaminating the Salamina and Athens coastlines. Effects of the spill, and remediation efforts, on sediment microbial communities were quantified over the following 7 months. Five days post-spill, the concentration of measured hydrocarbons within surface sediments of contaminated beaches was 1,093-3,773 μg g dry sediment (91% alkanes and 9% polycyclic aromatic hydrocarbons), but measured hydrocarbons decreased rapidly after extensive clean-up operations.
View Article and Find Full Text PDFHydrated proteins exhibit a broad dielectric loss extending over the frequency range from 1 MHz to 10 GHz which can be decomposed into a number of constituent dispersions. One of these dispersions with a relaxation time of approximately 18 ns has been attributed to the relaxation of protein backbone peptide groups in the protein interior. In the work reported here, this dielectric dispersion was investigated as a function of temperature for the enzyme glucose oxidase.
View Article and Find Full Text PDFA new method for the retrieval of the spectral refractive indices of micrometer-sized particles from infrared aerosol extinction spectra has been developed. With this method we use a classical damped harmonic-oscillator model of molecular absorption in conjunction with Mie scattering to model extinction spectra, which we then fit to the measurements using a numerical optimal estimation algorithm. The main advantage of this method over the more traditional Kramers-Kronig approach is that it allows the full complex refractive-index spectra, along with the parameters of the particle size distribution, to be retrieved from a single extinction spectrum.
View Article and Find Full Text PDFAnalytical expressions are found for the derivatives of commonly used Mie scattering parameters, in particular the absorption and the scattering efficiencies, and for the angular intensity functions. These expressions are based on the analytical derivatives of the Mie scattering amplitudes a(n) and b(n) with respect to the particle size parameter and complex refractive index. In addition, analytical derivatives are found for the volume absorption and scattering coefficients, as well as for the intensity functions of a population of particles with log normal size distribution.
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