Sensitive Detection and Quantification of Oxygenated Compounds in Complex Samples Using GC-Combustion-MS.

This work introduces a new element-selective gas chromatography detector for the accurate quantification of traces of volatile oxygen-containing compounds in complex samples without the need for specific standards. The key to this approach is the use of oxygen highly enriched in O as the oxidizing gas in a combustion unit (800 °C) that allows us to directly and unambiguously detect the natural oxygen present in the GC-separated compounds through its incorporation into the volatile species formed after their combustion and their subsequent degradation to O in the ion source. The unspecific signal due to the low O abundance in the oxidizing gas could be compensated by measuring the / 12 that comes as well from the CO degradation.

Frequency-Dependent Squeezed Vacuum Source for the Advanced Virgo Gravitational-Wave Detector.

In this Letter, we present the design and performance of the frequency-dependent squeezed vacuum source that will be used for the broadband quantum noise reduction of the Advanced Virgo Plus gravitational-wave detector in the upcoming observation run. The frequency-dependent squeezed field is generated by a phase rotation of a frequency-independent squeezed state through a 285 m long, high-finesse, near-detuned optical resonator. With about 8.

Potential of GC-Combustion-MS as a Powerful and Versatile Nitrogen-Selective Detector in Gas Chromatography.

Here, we show the potential and applicability of the novel GC-combustion-MS approach as a nitrogen-selective GC detector. Operating requirements to achieve reproducible and compound-independent formation of volatile NO species as a selective N-signal during the combustion step are described. Specifically, high temperatures (≥1000 °C) and post-column O flows (0.

Massive Galaxy Clusters Like El Gordo Hint at Primordial Quantum Diffusion.

It is generally assumed within the standard cosmological model that initial density perturbations are Gaussian at all scales. However, primordial quantum diffusion unavoidably generates non-Gaussian, exponential tails in the distribution of inflationary perturbations. These exponential tails have direct consequences for the formation of collapsed structures in the Universe, as has been studied in the context of primordial black holes.

Probing the nature of black holes: Deep in the mHz gravitational-wave sky.

Black holes are unique among astrophysical sources: they are the simplest macroscopic objects in the Universe, and they are extraordinary in terms of their ability to convert energy into electromagnetic and gravitational radiation. Our capacity to probe their nature is limited by the sensitivity of our detectors. The LIGO/Virgo interferometers are the gravitational-wave equivalent of Galileo's telescope.

Dark Energy Survey Year 1 Results: Cosmological Constraints from Cluster Abundances, Weak Lensing, and Galaxy Correlations.

We present the first joint analysis of cluster abundances and auto or cross-correlations of three cosmic tracer fields: galaxy density, weak gravitational lensing shear, and cluster density split by optical richness. From a joint analysis (4×2pt+N) of cluster abundances, three cluster cross-correlations, and the auto correlations of the galaxy density measured from the first year data of the Dark Energy Survey, we obtain Ω_{m}=0.305_{-0.

Constraints on Dark Matter Properties from Observations of Milky Way Satellite Galaxies.

We perform a comprehensive study of Milky Way (MW) satellite galaxies to constrain the fundamental properties of dark matter (DM). This analysis fully incorporates inhomogeneities in the spatial distribution and detectability of MW satellites and marginalizes over uncertainties in the mapping between galaxies and DM halos, the properties of the MW system, and the disruption of subhalos by the MW disk. Our results are consistent with the cold, collisionless DM paradigm and yield the strongest cosmological constraints to date on particle models of warm, interacting, and fuzzy dark matter.

Detection of Cross-Correlation between Gravitational Lensing and γ Rays.

In recent years, many γ-ray sources have been identified, yet the unresolved component hosts valuable information on the faintest emission. In order to extract it, a cross-correlation with gravitational tracers of matter in the Universe has been shown to be a promising tool. We report here the first identification of a cross-correlation signal between γ rays and the distribution of mass in the Universe probed by weak gravitational lensing.

Quantitative multiplexed elemental (C, H, N and S) detection in complex mixtures using gas chromatography.

We present a novel and single detection approach that enables sensitive, accurate and compound-independent quantification of N, S and H in the individual compounds present in complex samples. Integration of the whole chromatographic profile gives the total content of the elements. Simultaneous universal detection is also achieved using the C profile.

Detection of CMB-Cluster Lensing using Polarization Data from SPTpol.

We report the first detection of gravitational lensing due to galaxy clusters using only the polarization of the cosmic microwave background (CMB). The lensing signal is obtained using a new estimator that extracts the lensing dipole signature from stacked images formed by rotating the cluster-centered Stokes QU map cutouts along the direction of the locally measured background CMB polarization gradient. Using data from the SPTpol 500  deg^{2} survey at the locations of roughly 18 000 clusters with richness λ≥10 from the Dark Energy Survey (DES) Year-3 full galaxy cluster catalog, we detect lensing at 4.

Primordial black holes and the origin of the matter-antimatter asymmetry.

We review here a new scenario of electroweak baryogenesis where the local energy released in the gravitational collapse to form primordial black holes (PBHs) at the quark-hadron (QCD) epoch drives over-the-barrier sphaleron transitions in a far from equilibrium environment with just the standard model CP violation. Baryons are efficiently produced in relativistic collisions around the black holes and soon redistribute to the rest of the universe, generating the observed matter-antimatter asymmetry well before primordial nucleosynthesis. Therefore, in this scenario there is a common origin of both the dark matter to baryon ratio and the photon to baryon ratio.

Cosmological Constraints from Multiple Probes in the Dark Energy Survey.

The combination of multiple observational probes has long been advocated as a powerful technique to constrain cosmological parameters, in particular dark energy. The Dark Energy Survey has measured 207 spectroscopically confirmed type Ia supernova light curves, the baryon acoustic oscillation feature, weak gravitational lensing, and galaxy clustering. Here we present combined results from these probes, deriving constraints on the equation of state, w, of dark energy and its energy density in the Universe.

GC-ICP-MS/MS Instrumental Setup for Total and Speciation Sulfur Analysis in Gasolines using Generic Standards.

Quantitative characterization of sulfur-containing petroleum derivatives is mainly limited by the large number of potential targets present and the matrix effects suffered due to the high-carbon-containing matrices. Herein we describe the instrumental modifications required in a commercial GC-ICP-MS/MS instrument, and their corresponding optimization, for turning it into a compound-independent quantitative technique for both total and speciation sulfur analysis in gasolines. Additionally, carbon-derived matrix effects were made negligible for direct and fast total S analysis, making the use of relatively complex isotope-dilution strategies not necessary anymore.

Signatures of Higgs dilaton and critical Higgs inflation.

We test the Higgs dilaton inflation model (HDM) using the latest cosmological datasets, including the cosmic microwave background temperature, polarization and lensing data from the satellite (2015), the BICEP and Keck Array experiments, the type Ia supernovae from the JLA catalogue, the baryon acoustic oscillations from CMASS, LOWZ and 6dF, the weak lensing data from the CFHTLenS survey and the matter power spectrum measurements from the latest SDSS data release. We find that the values of all cosmological parameters allowed by the HDM are well within the satellite (2015) constraints. In particular, we determine [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text] and [Formula: see text] (at 95.

Cosmology and Fundamental Physics with the Euclid Satellite.

Euclid is a European Space Agency medium-class mission selected for launch in 2019 within the Cosmic Vision 2015-2025 program. The main goal of Euclid is to understand the origin of the accelerated expansion of the universe. Euclid will explore the expansion history of the universe and the evolution of cosmic structures by measuring shapes and red-shifts of galaxies as well as the distribution of clusters of galaxies over a large fraction of the sky.

Magnetic field production during preheating at the electroweak scale.

We study the generation of magnetic fields during preheating within a scenario of hybrid inflation at the electroweak scale. We find that the nonperturbative and strongly out-of-equilibrium process of generation of magnetic fields with a nontrivial helicity occurs along the lines predicted by Vachaspati many years ago. The magnitude (rho_{B}/rho_{EW} approximately 10{-2}) and correlation length of these helical magnetic fields grow linearly with time during preheating and are consistent with the possibility that these seeds gave rise to the microgauss fields observed today in galaxies and clusters of galaxies.

Stochastic background of gravitational waves from hybrid preheating.

The process of reheating the Universe after hybrid inflation is extremely violent. It proceeds through the nucleation and subsequent collision of large concentrations of energy density in bubblelike structures, which generate a significant fraction of energy in the form of gravitational waves. We study the power spectrum of the stochastic background of gravitational waves produced at reheating after hybrid inflation.

Gauge-invariant inflaton in the minimal supersymmetric standard model.

We argue that all the necessary ingredients for successful inflation are present in the flat directions of the Minimally Supersymmetric Standard Model. We show that out of many gauge-invariant combinations of squarks, sleptons, and Higgs bosons, there are two directions, LLe and udd, which are promising candidates for the inflaton. The model predicts more than 10(3) e-foldings, with an inflationary scale of H(inf) approximately O(1-10) GeV, provides a tilted spectrum with an amplitude of delta(H) approximately 10(-5) and a negligible tensor perturbation.

Bounds on isocurvature perturbations from cosmic microwave background and large scale structure data.

We obtain very stringent bounds on the possible cold dark matter, baryon, and neutrino isocurvature contributions to the primordial fluctuations in the Universe, using recent cosmic microwave background and large scale structure data. Neglecting the possible effects of spatial curvature, tensor perturbations, and reionization, we perform a Bayesian likelihood analysis with nine free parameters, and find that the amplitude of the isocurvature component cannot be larger than about 31% for the cold dark matter mode, 91% for the baryon mode, 76% for the neutrino density mode, and 60% for the neutrino velocity mode, at 2sigma, for uncorrelated models. For correlated adiabatic and isocurvature components, the fraction could be slightly larger.

Dynamics of symmetry breaking and tachyonic preheating.

We reconsider the old problem of the dynamics of spontaneous symmetry breaking (SSB) using 3D lattice simulations. We develop a theory of tachyonic preheating, which occurs due to the spinodal instability of the scalar field. Tachyonic preheating is so efficient that SSB typically completes within a single oscillation as the field rolls towards the minimum of its effective potential.