Preparation of Thermochromic Vanadium Dioxide Films Assisted by Machine Learning.

In recent years, smart windows have attracted widespread attention due to their ability to respond to external stimuli such as light, heat, and electricity, thereby intelligently adjusting the ultraviolet, visible, and near-infrared light in solar radiation. VO(M) undergoes a reversible phase transition from an insulating phase (monoclinic, M) to a metallic phase (rutile, R) at a critical temperature of 68 °C, resulting in a significant difference in near-infrared transmittance, which is particularly suitable for use in energy-saving smart windows. However, due to the multiple valence states of vanadium ions and the multiphase characteristics of VO, there are still challenges in preparing pure-phase VO(M).

Enhanced Fluorescence and Environmental Stability of Red-Emissive Carbon Dots via Chemical Bonding with Cellulose Films.

The development of red emission carbon dots with bright solid-state fluorescence would significantly broaden their application in optoelectronic devices and sensors. Herein, a red-emissive carbon dot-based nanocomposite has been synthesized through chemical bonding with cellulose films. The red emission originating from the surface states of carbon dots was maintained in the cellulose films.

Enhancing the Electron Transport, Quantum Yield, and Catalytic Performance of Carbonized Polymer Dots via MnO Bridges.

Carbonized polymer dots (CPDs) have received tremendous attention during the last decade due to their excellent fluorescent properties and catalytic performance. Doping CPDs with transition metal atoms accelerates the local electron flow in CPDs and improves the fluorescent properties and catalytic performance of the CPDs. However, the binding sites and the formation mechanisms of the transition-metal-atom-doped CPDs remain inconclusive.