Active Perception in Non-Visual Recognition Environments by Stretchable Tentacle Sensor Arrays.

Smoke fog or other light-interference environments have intrinsic obstruction for visual recognition techniques to explore objects and surroundings. Alternatively, tactile perceptions, rather than visual observations, are commonly used by burrowing or deep-sea animals to communicate with environments. Bio-inspired by this natural wisdom, here, we demonstrate stretchable tentacle sensor arrays, which can recognize surrounding objects located in non-visual conditions such as smoke fog or dark environment.

Localized Electrons Enhanced Ion Transport for Ultrafast Electrochemical Energy Storage.

The rate-determining process for electrochemical energy storage is largely determined by ion transport occurring in the electrode materials. Apart from decreasing the distance of ion diffusion, the enhancement of ionic mobility is crucial for ion transport. Here, a localized electron enhanced ion transport mechanism to promote ion mobility for ultrafast energy storage is proposed.

Intrinsically reversible superglues via shape adaptation inspired by snail epiphragm.

Adhesives are ubiquitous in daily life and industrial applications. They usually fall into one of two classes: strong but irreversible (e.g.

Ultrastable Underwater Anti-Oil Fouling Coatings from Spray Assemblies of Polyelectrolyte Grafted Silica Nanochains.

Surfaces that have superhydrophilic characteristics are known to exhibit extreme oil repellency under water, which is attractive for applications including anti-fogging, water-oil separations, and self-cleaning. However, superhydrophilic surfaces can also be easily fouled and lose their extreme oil repellency, which limits their usage in practical applications. In this work, we create an anti-oil fouling coating by spray coating poly(acrylic acid) (PAA)-grafted SiO nanochains (approximately 45 nm wide and 300 nm long) onto solid surfaces, forming a nanoporous film exhibiting superhydrophilicity (water contact angle in air ≈ 0°) and underwater superoleophobicity (dichloroethane contact angle ≥ 165°).

Colloidal inks from bumpy colloidal nanoparticles for the assembly of ultrasmooth and uniform structural colors.

Angle-independent structural colors obtained from colloidal nanoparticles (NPs) are of interest for potential applications in displays, color printing, 3D printing, and direct writing. However, it remains challenging to prepare uniform structural colors that can be directly written from colloidal inks that not only have no coffee-ring effect, but also have ultrasmooth film thickness, which will be important for layer-by-layer stacking. Herein, we synthesize polypyrrole (PPy) black coated silica NPs that have a low coverage (∼10.

Cuts Guided Deterministic Buckling in Arrays of Soft Parallel Plates for Multifunctionality.

Harnessing buckling instability in soft materials offers an effective strategy to achieve multifunctionality. Despite great efforts in controlling the wrinkling behaviors of film-based systems and buckling of periodic structures, the benefits of classical plate buckling in soft materials remain largely unexplored. The challenge lies in the intrinsic indeterminate characteristics of buckling, leading to geometric frustration and random orientations.

Varying and unchanging whiteness on the wings of dusk-active and shade-inhabiting butterflies.

Whiteness, although frequently apparent on the wings, legs, antennae, or bodies of many species of moths and butterflies, along with other colors and shades, has often escaped our attention. Here, we investigate the nanostructure and microstructure of white spots on the wings of , a dusk-active and shade-inhabiting Costa Rican rain forest butterfly (Hesperiidae). On both males and females, two types of whiteness occur: angle dependent (dull or bright) and angle independent, which differ in the microstructure, orientation, and associated properties of their scales.

Confined Assemblies of Colloidal Particles with Soft Repulsive Interactions.

We investigate the microconfinement of charged silica nanoparticles dispersed in refractive index matching monomers in poly(dimethylsiloxane) (PDMS) porous membrane. Here, the silica colloidal particles interact with each other and the pore wall via electrostatic double layer forces. Different from the hard sphere systems where the assembled morphologies are prescribed by the diameter ratio between the cylindrical confinement and the nanoparticles, here we observe a much richer variety of assemblies that are highly sensitive to both bulk and local nanoparticle concentration with fixed particle size and channel size.

Carrier Step-by-Step Transport Initiated by Precise Defect Distribution Engineering for Efficient Photocatalytic Hydrogen Generation.

Semiconductor photocatalysts have been widely used for solar-to-hydrogen conversion; however, efficient photocatalytic hydrogen generation still remains a challenge. To improve the photocatalytic activity, the critical step is the transport of photogenerated carriers from bulk to surface. Here, we report the carrier step-by-step transport (CST) for semiconductor photocatalysts through precise defect engineering.

Production of Structural Colors with High Contrast and Wide Viewing Angles from Assemblies of Polypyrrole Black Coated Polystyrene Nanoparticles.

Structural color with wide viewing angles has enormous potential applications in pigment, ink formulation, displays, and sensors. However, colors obtained from colloidal assemblies with low refractive index contrast or without black additives typically appear pale. Here, we prepare polypyrrole (PPy) black coated polystyrene (PS) nanoparticles and demonstrate well-defined colors with high color contrast and wide viewing angles under ambient light.

A high-efficiency superhydrophobic plasma separator.

To meet stringent limit-of-detection specifications for low abundance target molecules, a relatively large volume of plasma is needed for many blood-based clinical diagnostics. Conventional centrifugation methods for plasma separation are not suitable for on-site testing or bedside diagnostics. Here, we report a simple, yet high-efficiency, clamshell-style, superhydrophobic plasma separator that is capable of separating a relatively large volume of plasma from several hundred microliters of whole blood (finger-prick blood volume).

Directing the deformation paths of soft metamaterials with prescribed asymmetric units.

By prescribing asymmetric ligaments with different arrangements in elastomeric porous membranes of pre-twisted kagome lattices, the buckling instability is avoided, allowing for smooth and homogenous structural reconfiguration in a deterministic fashion. The stress-strain behaviors and negative Poisson's ratios can be tuned by the pre-twisting angles.

Buckling, symmetry breaking, and cavitation in periodically micro-structured hydrogel membranes.

We investigated swelling induced instabilities in porous membranes with a square array of micron-sized circular holes prepared from a pH and temperature dual-responsive hydrogel, poly(2-hydroxyethyl methacrylate-co-N-isopropylacrylamide-co-acrylic acid) (PHEMA-co-PNIPAAm-co-PAA). At room temperature (25 °C), the hydrogel swelled to ∼1.5 to 8 times of its dried volume when pH was increased from 2 to 7.

Spray coating of superhydrophobic and angle-independent coloured films.

Angle-independent coloured films with superhydrophobicity were fabricated from quasi-amorphous arrays of monodispersed fluorinated silica nanoparticles via one-step spray coating. The film exhibited a high contact angle (>150°) and a low roll-off angle (~2°) and the colour could be tuned to blue, green and moccasin by varying the size of the nanoparticles.

In situ plasmonic counter for polymerization of chains of gold nanorods in solution.

Self-assembly of gold nanorods (NRs) in linear, polymer-like chains offers the ability to test and validate theoretical models of molecular polymerization. Practically, NR chains show multiple promising applications in sensing of chemical and biological species. Both areas of research can strongly benefit from the development of a quantitative tool for characterization of the structure of NR chains in the course of self-assembly, based on the change in ensemble-averaged optical properties of plasmonic polymers; however, quantitative correlation between the extinction spectra and the structural characteristics of NR chains has not been reported.