Integrating Transcriptome and Metabolome Analyses Revealed Salinity Induces Arsenobetaine Biosynthesis in Marine Medaka ().

Marine fish exhibit elevated levels of arsenobetaine (AsB), while the impact and underlying mechanism of salinity on AsB biosynthesis remain inadequately explored. In this study, marine medaka (), typically inhabiting 30‰ high salinity, were gradually acclimated to low salinities of 20, 10, and 0‰. Following acclimation, the fish were exposed to arsenate (As(V)) in their diet for 30 days.

Comprehensive strategies for microcystin degradation: A review of the physical, chemical, and biological methods and genetic engineering.

Addressing the threat of harmful cyanobacterial blooms (CyanoHABs) and their associated microcystins (MCs) is crucial for global drinking water safety. In this review, we comprehensively analyze and compares the physical, chemical, and biological methods and genetic engineering for MCs degradation in aquatic environments. Physical methods, such as UV treatments and photocatalytic reactions, have a high efficiency in breaking down MCs, with the potential for further enhancement in performance and reduction of hazardous byproducts.

Enhanced removal of trace thallium by photo-promoted adsorption using Prussian blue@filter papers: Performance and mechanistic insights.

Developing highly efficient adsorbents for the removal of trace thallium(I) (Tl) is crucial for addressing environmental challenges. In this study, we successfully synthesized cubic Prussian blue (PB) loading on filter papers using an intermediate layer (dopamine/polyethyleneimine) via in-situ methods. The as-prepared PB-modified FP demonstrated outstanding anti-interference properties and light-enhanced adsorption performance for Tl (0.

Remediation of arsenic-contaminated soil using nanoscale schwertmannite synthesized by persulfate oxidation with carboxymethyl cellulose stabilization.

Schwertmannite (SCH) is a promising material for adsorbing inorganic arsenic (As). We synthesized SCH nanoparticles (nano-SCH) via a modified chemical oxidation method and investigated the application of nano-SCH for the remediation of As-contaminated soils. The production of nano-SCH was successfully prepared using the persulfate oxidation method with carboxymethyl cellulose stabilization.

Reduction and adsorption of uranium(VI) from aqueous solutions using nanoscale zero-valent manganese.

Nano zero-valent manganese (nZVMn) is theoretically expected to exhibit high reducibility and adsorption capacity, yet its feasibility, performance, and mechanism for reducing and adsorbing hexavalent uranium (U(VI)) from wastewater remain unclear. In this study, nZVMn was prepared via borohydride reduction, and its behaviors about reduction and adsorption of U(VI), as well as the underlying mechanism, were investigated. Results indicated that nZVMn exhibited a maximum U(VI) adsorption capacity of 625.

Thallium removal from wastewater using sulfidized zero-valent manganese: Effects of sulfidation method and liquid nitrogen pretreatment.

Zero-valent manganese (ZVMn) possesses high reducibility in theory, while sulfide exhibits strong affinity towards a variety of heavy metals owing to the low solubility of metal sulfides. Yet the performance and mechanisms on using sulfidized zero-valent manganese (SZVMn) to remove thallium (Tl) from wastewater still remain unclear. In this study, the performance of Tl(I) removal using SZVMn synthesized by borohydrides reduction followed by sulfides modification, with and without liquid nitrogen treatment, was compared and the mechanism behind was investigated.

Efficient removal of antimonate and antimonite by a novel lanthanum-manganese binary oxide: Performance and mechanism.

Antimony is a highly toxic pollutant and its removal from water gains increasing attention. To effectively remove both Sb(III) and Sb(V), a novel lanthanum-manganese binary oxide (LMBO) adsorbent was synthesized by a simple oxidation coupled with precipitation method. The as-prepared LMBO was detailedly characterized by the XRD, SEM, TEM, BET, FTIR and XPS techniques.

Oil/water separation using elastic bio-aerogels derived from bagasse: Role of fabrication steps.

Bio-aerogels hold great promise for selective oil separation from water due to their light weight and high sustainability. However, how the fabrication methods impact the elasticity and oil sorption performance of bio-aerogels still needs systematic comparison and in-depth investigation. In this study, the fabrication of hydrophobic bio-aerogels with good elasticity and reusability was optimized using a factorial design based on the dosages of bagasse-derived cellulose nanofiber, sodium alginate, and calcium carbonate.

Confining Nano-FeO in the Superhydrophilic Membrane Skin Layer to Minimize Internal Fouling.

Membrane surface fouling is often reversible as it can be mitigated by enhancing the crossflow shear force. However, membrane internal fouling is often irreversible and thus more challenging. In this study, we developed a new superhydrophilic poly(vinylidene fluoride) (P-PVDF) membrane confined with nano-FeO in the top skin layer via reverse filtration to reduce internal fouling.

Efficient Sorption of Arsenic on Nanostructured Fe-Cu Binary Oxides: Influence of Structure and Crystallinity.

To study the structure-performance relationship, a series of nanostructured Fe-Cu binary oxides (FCBOs) were prepared by varying synthesis conditions. The obtained binary oxides were well characterized using X-ray diffraction (XRD), transmission electron microscope (TEM), Brunner-Emmet-Teller (BET), magnetic and Zeta potential measurement techniques. Both As(V) and As(III) sorption on the FCBOs were evaluated by batch tests.

Highly efficient removal of thallium(I) by facilely fabricated amorphous titanium dioxide from water and wastewater.

In this study, amorphous hydrous titanium dioxide was synthesized by a facile precipitation method at room temperature, aiming to effectively remove thallium(I) from water. The titanium dioxide prepared using ammonia as precipitant (TiO) is more effective for thallium(I) uptake than the one synthesized with sodium hydroxide (TiO). The TiO obtained particles are amorphous, aggregates of many nanoparticles and irregular in shape.

Uptake, organ distribution and health risk assessment of potentially toxic elements in crops in abandoned indigenous smelting region.

Inorganic pollution induced by smelting waste has threatened the safety of environment, whereas the impacts on farmlands with regards to potentially toxic elements (PTEs) receive insufficient attention. Herein, the contents, transfer pathways and potential risks of the PTEs in common crops were examined from different farmlands distributed around an indigenous Zn-smelting area in Guizhou, China. The results showed that Tl in cabbage (Brassica oleracea L.

Multi-step purification of electrolytic manganese residue leachate using hydroxide sedimentation, struvite precipitation, chlorination and coagulation: Advanced removal of manganese, ammonium, and phosphate.

Water pollution caused by the release of manganese (Mn) and ammonia nitrogen (NH-N) from electrolytic manganese residue (EMR) generated from industrial activities poses a serious threat to ecosystems and human health. In this study, an integrated process consisting sequentially of hydroxide sedimentation, struvite precipitation, breakpoint chlorination, and ferric chloride coagulation was optimized to remove Mn and NH-N from EMR leachate, and to address the issue of residual orthophosphate caused by struvite precipitation. The precipitates were characterized using X-ray diffraction, scanning electron microscopy, and thermogravimetric analyses.

Carbon quantum dots derived from the extracellular polymeric substance of anaerobic ammonium oxidation granular sludge for detection of trace Mn(vii) and Cr(vi).

Carbon quantum dots (CQDs) were synthesized a hydrothermal method, in which extracellular polymeric substance (EPS) from anaerobic ammonium oxidation (anammox) granular sludge was used as a carbon precursor, while citric acid and ethylenediamine were applied as auxiliary carbon source and passivation agent, respectively. The synthesized CQDs, with orderly spherical shape and mean size of 7.15 nm, emitted blue fluorescent light under UV radiation of 365 nm.

Highly efficient removal of thallium(I) from wastewater via hypochlorite catalytic oxidation coupled with adsorption by hydrochar coated nickel ferrite composite.

In this study, tannery wastewater was used as carbon source to hydrothermally synthesize magnetic carbon-coated nickel ferrite composite (NiFeO@C), which was employed as a catalyst for thallium (Tl) oxidation by hypochlorite and simultaneously as an adsorbent for Tl removal from wastewater. Compared with NiFeO@C adsorption or hypochlorite oxidation alone, the combination of NiFeO@C and hypochlorite substantially enhanced the rate and efficiency of Tl(I) removal. In addition, this process was highly effective for Tl(I) removal over a wide pH range (6-12).

Zero-valent iron-manganese bimetallic nanocomposites catalyze hypochlorite for enhanced thallium(I) oxidation and removal from wastewater: Materials characterization, process optimization and removal mechanisms.

Nano zero-valent metals adsorption coupled with advanced oxidation for environmental pollutants removal has been gaining attention recently. In this study, zero-valent iron-manganese (nZVIM) bimetallic nanocomposites were prepared via one-pot borohydride reduction and coupled with hypochlorite (ClO) oxidation for enhanced thallium (Tl) removal from wastewater. Amorphous nZVIM nanoparticles were successfully synthesized, with a specific surface area of 106.

Hyperaccumulation and transport mechanism of thallium and arsenic in brake ferns (Pteris vittata L.): A case study from mining area.

Both thallium (Tl) and arsenic (As) bear severe toxicity. Brake fern (Pteris vittata L.) is well-known for its hyperaccumulation capacity of As, yet its role on Tl accumulation remains unknown.

Synthesis of manganese dioxide with different morphologies for thallium removal from wastewater.

Manganese dioxide (MnO) with different morphologies (tube-, wire-, rod-, and flower-like) was synthesized via hydrothermal method and then applied for thallium (Tl) removal from wastewater. During material synthesis, short reaction time (6 h) and low temperature (110 °C) were prone to form polycrystalline flower-like birnessite type MnO, while long reaction time (24 h) and high temperature (240 °C) were inclined to produce polycrystalline wire-like birnessite type MnO. Moderate reaction time (12 h) with low temperature at 120 °C/140 °C led to formation of mono-crystalline rod- and tube-like α-MnO respectively.

Enhanced thallium(I) removal from wastewater using hypochlorite oxidation coupled with magnetite-based biochar adsorption.

The development of efficient and regenerable adsorbent coupled with advanced oxidation for enhanced thallium (Tl) removal has been a recent focus on wastewater treatment. In this study, a magnetite-based biochar derived from watermelon rinds was synthesized and used as a sustainable adsorbent and catalyst for hypochlorite oxidation and removal of Tl(I) from wastewater. The addition of hypochlorite substantially enhanced the Tl(I) removal under normal pH range (6-9).

Novel nanostructured Fe-Cu-Al trimetal oxide for enhanced antimony(V) removal: synthesis, characterization and performance.

Given the adverse health effects of antimony (Sb), there is an increased focus on developing methods to remove this toxic metal from contaminated water bodies. To effectively remove Sb(V), a new nanostructured Fe-Cu-Al trimetal oxide was fabricated using co-precipitation method at ambient temperature. The Fe-Cu-Al trimetal oxide was very effective at removing Sb(V) from water; it had a maximal adsorption capacity of 169.

Neural Network-Based Adaptive Consensus Control for a Class of Nonaffine Nonlinear Multiagent Systems With Actuator Faults.

In this paper, the consensus problem is investigated for a class of nonaffine nonlinear multiagent systems (MASs) with actuator faults of partial loss of effectiveness fault and biased fault. To deal with the control difficulty caused by the nonaffine dynamics, a neural network (NN)-based adaptive consensus protocol is developed based on the Lyapunov analysis. The neuron input of the NN uses both the state information and the consensus error information.

Polyvinyl alcohol-stabilized granular Fe-Mn binary oxide as an effective adsorbent for simultaneous removal of arsenate and arsenite.

A novel granular Fe-Mn (GFM) binary oxide sorbent, with a diameter of approximate 2.0 mm and a length of 2.0-3.

Enhanced removal of arsenite and arsenate by a multifunctional Fe-Ti-Mn composite oxide: Photooxidation, oxidation and adsorption.

In order to attain a high-efficiency and low-cost adsorbent for both arsenate (As(V)) and arsenite (As(III)) removal from As-contaminated water, a novel nanostructured Fe-Ti-Mn composite oxide (FTMO) was fabricated through a one-step simultaneous oxidation and co-precipitation method. Batch control experiments and series of spectroscopy detection technologies were carried out to investigate the surface change of the FTMO adsorbent and the respective role of Fe, Ti and Mn content in the arsenic adsorption process. The results showed that the FTMO adsorbent had a high adsorption capacity for both As(V) and As(III) (especially for the latter one) via the formation of inner-sphere complexes at the water/oxide interface under both darkness and light conditions.

Adaptive Sliding Mode Consensus Tracking for Second-Order Nonlinear Multiagent Systems With Actuator Faults.

This paper investigates the consensus tracking problem of second-order nonlinear multiagent systems (MAS) with disturbance and actuator fault by the sliding mode control method. The communication topology of the MAS is directed and only part of the followers have access to the leader's information. First, a discontinuous sliding mode tracking protocol is studied for consensus tracking of the MAS.