Current demand for waste recycling, phosphogypsum-based excess-sulphate slag cement (PESSC) as a sustainable cement prepared by solid wastes, urges enhancing its performance development based on microstructure optimisation. For the purpose of improving the performance and durability of PESSC used in normal or corrosive environments, it is deemed an efficient technique to produce iron-doped compounds with high thermodynamic stability. This paper presents a systematic study of the effect of iron modification on PESSC binders by introducing 0%-2% polyferric sulphate (PFS) from a multiscale viewpoint.
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