Low-power edge detection based on ferroelectric field-effect transistor.

Edge detection is one of the most essential research hotspots in computer vision and has a wide variety of applications, such as image segmentation, target detection, and other high-level image processing technologies. However, efficient edge detection is difficult in a resource-constrained environment, especially edge-computing hardware. Here, we report a low-power edge detection hardware system based on HfO-based ferroelectric field-effect transistor, which is one of the most potential non-volatile memories for energy-efficient computing.

Modulating Electron Density of Ni-N-C Sites by N-doped Ni for Industrial-level CO Electroreduction in Acidic Media.

Electro-chemically reducing CO in a highly acidic medium is promising for addressing the issue of carbonate accumulation. However, the hydrogen evolution reaction (HER) typically dominates the acidic CO reduction. Herein, we construct an efficient electro-catalyst for CO formation based on a core-shell structure, where nitrogen-doped Ni nanoparticles coexist with nitrogen-coordinated Ni single atoms.

Anchoring ultra-small molybdenum oxide species on covalent triazine frameworks for efficient electrochemical nitrogen fixation.

We report a smart ion-exchange strategy to anchor molybdenum oxide particles on charge-modulated conjugated triazine frameworks (Mo/CTF-I) for electrochemically fixing nitrogen. The strong interaction between MoO and CTF-I is conducive to the activation of the inert N molecule in the electro-chemical process. As a result, 5% Mo/CTF-I exhibited an excellent faradaic efficiency of 27.

Creating Frustrated Lewis Pairs in Defective Boron Carbon Nitride for Electrocatalytic Nitrogen Reduction to Ammonia.

The electrocatalytic nitrogen reduction reaction (NRR) on metal-free catalysts is an attractive alternative to the industrial Haber-Bosch process. However, the state-of-the-art metal-free electrocatalysts still suffer from low Faraday efficiencies and low ammonia yields. Herein, we present a molecular design strategy to develop a defective boron carbon nitride (BCN) catalyst with the abundant unsaturated B and N atoms as Lewis acid and base sites, which upgrades the catalyst from a single "Lewis acid catalysis" to "frustrated Lewis pairs (FLPs) catalysis.

New fused conjugated molecules with fused thiophene and pyran units for organic electronic materials.

Rigid and planar conjugated molecules have substantial significance due to their potential applications in organic electronics. Herein we report two highly fused ladder type conjugated molecules, TTCTTC and TTTCTTTC, with up to 10 fused rings in which the fused-thiophene rings are fused to the chromeno[6,5,4-]chromene unit. Both molecules show high HOMO levels and accordingly they can be oxidized into their radical cations with absorptions extending to 1300 nm in the presence of trifluoroacetic acid.

Dicyclohepta[ijkl,uvwx]rubicene with Two Pentagons and Two Heptagons as a Stable and Planar Non-benzenoid Nanographene.

Polycyclic aromatic hydrocarbons with hexagons/pentagons or hexagons/heptagons have been intensively investigated in recent years, but those with simultaneous presence of hexagons, pentagons and heptagons remain rare. In this paper, we report dicyclohepta[ijkl,uvwx]rubicene (DHR), a non-benzenoid isomer of dibenzo[bc,kl]coronene with two pentagons and two heptagons. We developed an efficient and scalable synthetic method for DHR by using Scholl reaction and dehydrogenation.

An A-D-A'-D-A Conjugated Molecule Entailing Diazapentalene Unit for an n-Type Organic Semiconductor.

Conjugated molecules with low lying LUMO levels are demanding for the development of air stable n-type organic semiconductors. In this paper, we report a new A-D-A'-D-A conjugated molecule (DAPDCV) entailing diazapentalene (DAP) and dicyanovinylene groups as electron accepting units. Both theoretical and electrochemical studies manifest that the incorporation of DAP unit in the conjugated molecule can effectively lower the LUMO energy level.