Propane wet reforming over PtSn nanoparticles on γ-AlO for acetone synthesis.

Acetone serves as an important solvent and building block for the chemical industry, but the current industrial synthesis of acetone is generally accompanied by the energy-intensive and costly cumene process used for phenol production. Here we propose a sustainable route for acetone synthesis via propane wet reforming at a moderate temperature of 350 C with the use of platinum-tin nanoparticles supported on γ-aluminium oxide (PtSn/γ-AlO) as catalyst. We achieve an acetone productivity of 858.

CO hydrogenation over Fe-Co bimetallic catalysts with tunable selectivity through a graphene fencing approach.

Tuning CO hydrogenation product distribution to obtain high-selectivity target products is of great significance. However, due to the imprecise regulation of chain propagation and hydrogenation reactions, the oriented synthesis of a single product is challenging. Herein, we report an approach to controlling multiple sites with graphene fence engineering that enables direct conversion of CO/H mixtures into different types of hydrocarbons.

High-Precision 3D-DIC Measurement Method Based on Improved Forward Newton Iteration.

To solve the problems of the traditional 3D-DIC algorithm based on feature information or FFT search at the expense of accuracy in exchange for time, such as error-point extraction, mismatching of feature points, poor robustness, and accuracy loss caused by poor anti-noise performance, an improved high-precision 3D-DIC measurement method was proposed. In this method, the exact initial value is obtained by an exhaustive search. Then, the forward Newton iteration method is used for pixel classification, and the first-order nine-point interpolation is designed, which can quickly obtain the elements of Jacobian and Hazen matrix, and achieve accurate sub-pixel positioning.

High-yield production of liquid fuels in CO hydrogenation on a zeolite-free Fe-based catalyst.

Catalytic conversion of CO to long-chain hydrocarbons with high activity and selectivity is appealing but hugely challenging. For conventional bifunctional catalysts with zeolite, poor coordination among catalytic activity, CO selectivity and target product selectivity often limit the long-chain hydrocarbon yield. Herein, we constructed a singly cobalt-modified iron-based catalyst achieving 57.

Boosting the synthesis of value-added aromatics directly from syngas a CrO and Ga doped zeolite capsule catalyst.

Even though the transformation of syngas into aromatics has been realized a methanol-mediated tandem process, the low product yield is still the bottleneck, limiting the industrial application of this technology. Herein, a tailor-made zeolite capsule catalyst with Ga doping and SiO coating was combined with the methanol synthesis catalyst CrO to boost the synthesis of value-added aromatics, especially -xylene, from syngas. Multiple characterization studies, control experiments, and density functional theory (DFT) calculation results clarified that Ga doped zeolites with strong CO adsorption capability facilitated the transformation of the reaction intermediate methanol by optimizing the first C-C coupling step under a high-pressure CO atmosphere, thereby driving the reaction forward for aromatics synthesis.

Selective Conversion of CO into para-Xylene over a ZnCr O -ZSM-5 Catalyst.

An oxide-zeolite (ZnCr O -ZSM-5) catalyst for directly converting CO to aromatics was designed and developed. It showed high PX/X (the C-mol ratio of p-xylene to all xylene) and PX/aromatics (the C-mol ratio of p-xylene to aromatics) ratios, which reached 97.3 and 63.

A Classification Method of Oracle Materials Based on Local Convolutional Neural Network Framework.

The classification of materials of oracle bone is one of the most basic aspects for oracle bone morphology. However, the classification method depending on experts' experience requires long-term learning and accumulation for professional knowledge. This article presents a multiregional convolutional neural network to classify the rubbings of oracle bones.

Direct and Oriented Conversion of CO into Value-Added Aromatics.

The oriented conversion of CO into target high-value chemicals is an effective way to reduce carbon emissions, but still presents a challenge. In this communication, we report the oriented conversion of CO into value-added aromatics, especially para-xylene, in a single pass by combining core-shell structured Zn-doped H-ZSM-5 (Zn-ZSM-5@SiO ) and a Cr O component. Through precise regulation of the acidity of Zn-ZSM-5@SiO , high para-xylene selectivity (38.

Snail as a key regulator of PRL-3 gene in colorectal cancer.

The regulators of a key metastasis gene PRL-3 in colorectal cancer (CRC) are still largely unknown. We found three potential binding sites of Snail, a key transcriptional factor involved in the epithelial-mesenchymal transition (EMT), in the region of PRL-3 promoter (located at -642 to -383). Moreover, our results showed that one of the Snail binding sites (located at -624 to -619) was the key element to maintain promoter activity of human PRL-3 gene.

Over-expression of CDH22 is associated with tumor progression in colorectal cancer.

CDH22, a member of the cadherins family, is highly expressed in the pituitary gland and the brain. It has been previously found that CDH22 is involved in morphogenesis and tissue formation in neural and non-neural cells of the brain and neuroendocrine organ. However, little is known about its role in colorectal cancer.

PRL-3 promotes epithelial mesenchymal transition by regulating cadherin directly.

PRL-3 is a key gene associated with progression and metastasis of colorectal cancer. Recently PRL-3 was suggested to promote epithelial mesenchymal transition (EMT) by downregulating E-cadherin expression. But the mechanisms of EMT induced by PRL-3 remain largely unknown.

[Expression of the zinc finger transcriptional factor Snail in colorectal carcinoma and its significance].

Objective: To study expression of the zinc finger transcriptional factor Snail in colorectal carcinoma and its significance.

Methods: Expressions of Snail in colorectal carcinoma SW480 and SW620 cells were assayed by immunocytochemistry and immunofluorescent cytochemistry. The paraffin-embedded specimens from 68 cases of colorectal carcinoma and its corresponding adjacent tissues, 33 cases of adenoma and 35 cases of metastatic lymph nodes were also examined for Snail expressions using immunohistochemistry.