Synthesis and Characterization of Metallo-Supramolecular Polymers Based on Benzodipyrrolidone.

A simple route to the preparation of benzodipyrrolidone (BDP) based monomeric building blocks containing 2,2':6',2″-terpyridines is reported from a common precursor 4'-(4-pinacolatoboronphenyl)-2,2':6',2″-terpyridine via Suzuki coupling reaction. Self-assembly polymerization with ruthenium (II) ions under mild conditions yielded a series of novel metallo-supramolecular polymers with weak donor-acceptor (D-A) structures based on benzodipyrrolidone. The structure of the bridge connected BDP with terpyridine have a significant impact on the wavelength and intensity of the intramolecular charge transfer (ICT) absorption peak.

Terpyridine-Containing π-Conjugated Polymers for Light-Emitting and Photovoltaic Materials.

2,2':6',2″-Terpyridine (tpy) is a versatile moiety used in the construction of small novel molecules or polymers. Extending or coupling tpy with π-conjugation structures can result in interesting optoelectronic properties. This mini-review summarizes the significant progress made over the past decades in the study of tpy-containing π-conjugated polymers and their application in light-emitting and photovoltaic materials.