Novel MoS-InO-WS (2D/3D/2D) ternary heterostructure nanocomposite material: Efficient photocatalytic degradation of antimicrobial agents under visible-light.

Fabrication of ternary composited photocatalytic nanomaterials with strong interaction is vital to deriving the fast charge separation for efficient photodegradation of organic contaminants in wastewater under visible light. In this work, novel ternary 2D/3D/2D MoS-InO-WS multi-nanostructures were synthesized using facile hydrothermal processes. XRD, FTIR, and XPS results confirmed the phase, functional groups, and element composition of pure MoS, MoS-InO and MoS-InO-WS hybrids.

Facile analysis of mycotoxin in coffee and tea samples using a novel semi-automated in-syringe based fast mycotoxin extraction (FaMEx) technique coupled with direct-injection ESI-MS/MS analysis.

Unlabelled: Identifying the risk of ochratoxin A in our daily food has become fundamental because of its toxicity. In this work, we report a novel semi-automated in-syringe-based fast mycotoxin extraction (IS-FaMEx) technique coupled with direct-injection electrospray-ionization tandem mass spectrometer (ESI-MS/MS) detection for the quantification of ochratoxin A in coffee and tea samples. Under the optimized conditions, the results reveal that the developed method's linearity was more remarkable, with a correlation coefficient of > 0.

Ultra-sensitive determination of Ochratoxin A in coffee and tea samples using a novel semi-automated in-syringe based coagulant-assisted fast mycotoxin extraction (FaMEx) technique coupled with UHPLC-MS/MS.

In this study, we demonstrated a novel semi-automated in-syringe-based coagulant-assisted liquid-liquid microextraction (IS-CGA-LLME) as fast mycotoxin extraction (FaMEx) technique coupled with ultra-high-performance liquid chromatography connected with a tandem-mass spectrometer (UHPLC-MS/MS) for the quantification of mycotoxin (Ochratoxin A, OT-A) in coffee and tea samples. IS-CGA-LLME is a three-step extraction process that includes extraction of OT-A from sample matrix using low-volume solvent extraction, then the extractant was cleaned-up using a coagulation process, and finally, the decolorized/matrix removed sample solution was processed for LLME for target analyte's pre-concentration. The final extractant was analyzed using UHPLC-MS/MS for OT-A quantification.

Rapid Identification and Analysis of Ochratoxin-A in Food and Agricultural Soil Samples Using a Novel Semi-Automated In-Syringe Based Fast Mycotoxin Extraction (FaMEx) Technique Coupled with UHPLC-MS/MS.

In this work, a fast mycotoxin extraction (FaMEx) technique was developed for the rapid identification and quantification of carcinogenic ochratoxin-A (OTA) in food (coffee and tea) and agricultural soil samples using ultra-high-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) detection. The FaMEx technique advancement is based on two plastic syringes integrated setup for rapid extraction and its subsequent controlled clean-up process. In the extraction process, a 0.

A low-cost eco-friendly fast drug extraction (FaDEx) technique for environmental and bio-monitoring of psychoactive drug in urban water and sports-persons' urine samples.

Nicotine is the most prominent psychoactive/addictive chemical substance consumed worldwide among young players in team sports. Moreover, urinary nicotine discharge and nicotine-based products disposal in environmental waters has been unavoidable in recent years. Therefore, sensitive monitoring of nicotine content in environmental waters and human urine samples is essential.

Novel fast pesticides extraction (FaPEx) strategy coupled with UHPLC-MS/MS for rapid monitoring of emerging pollutant fipronil and its metabolite in food and environmental samples.

In this work, we demonstrated a new, environmental-friendly and effective sample preparation strategy named 'in-syringe-assisted fast pesticides extraction (FaPEx)' technique coupled with LC-MS/MS for the rapid identification and monitoring of emerging pollutant fipronil and its metabolite fipronil sulfone in chicken egg and environmental soil samples. FaPEx strategy comprising of two simple steps. Firstly, the sample was placed in the syringe and extracted using low-volume acetonitrile with NaCl and anhydrous MgSO salts.

Sustainable approaches on industrial food wastes to value-added products - A review on extraction methods, characterizations, and its biomedical applications.

The concept of zero waste discharge has been gaining importance in recent years towards attaining a sustainable environment. Fruit processing industries generate millions of tons of byproducts like fruit peels and seeds, and their disposal poses an environmental threat. The concept of extracting value-added bioactive compounds from bio-waste is an excellent opportunity to mitigate environmental issues.

Synthesis and Characterization of High Viscosity Cationic Poly(Proline-Epichlorohydrin) Composite Polymer with Antibacterial Functionalities.

We report microbial resistance and catalytic activity of high viscosity cationic poly(proline-epichlorohydrin) composite (PRO-EPI) in the aqueous system. The PRO-EPI was prepared by a simple polycondensation, followed by FTIR, H NMR, SEM, DLS, viscosity, and DSC/TGA characterization. Several concentrations of the PRO-EPI were tested against Gram-negative ( and ) and Gram-positive () microorganisms.

Power density modulated ultrasonic degradation of perfluoroalkyl substances with and without sparging Argon.

The power density modulates the dynamics of the chemical reactions during the ultrasonic breakdown of organic compounds. We evaluated the ultrasonic degradation of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) at various power densities (30 W/L-262 W/L) with and without sparging Argon. We observed pseudo-first-order degradation kinetics at an initial PFASs concentration of 100 nM over a range of power density.

Kinetic model for sonolytic degradation of non-volatile surfactants: Perfluoroalkyl substances.

Sonolytic degradation kinetics of non-volatile surfactant perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) were investigated over a range of concentration, considering active cavity as a catalyst. The Michaelis-Menten type kinetic model was developed to empirically estimate the concentration of active cavity sites during reactions. Sonolytic degradation of PFOA and PFOS, as well as the formation of its inorganic constituents, fluoride, and sulfate, follows saturation kinetics of pseudo-first order at lower concentration (<2.

Plastic toys as a source of exposure to bisphenol-A and phthalates at childcare facilities.

Infants and toddlers are constantly exposed to toys at childcare facilities. Toys are made of a variety of plastics that often use endocrine-disrupting chemicals such as bisphenol-A (BPA) and phthalates as their building blocks. The goal of this study was to assess the non-dietary exposure of infants and toddlers to BPA and phthalates via leaching.

Steroid hormones in environmental matrices: extraction method comparison.

The U.S. Environmental Protection Agency (EPA) has developed methods for the analysis of steroid hormones in water, soil, sediment, and municipal biosolids by HRGC/HRMS (EPA Method 1698).

Evaluation of relative importance of ultrasound reactor parameters for the removal of estrogen hormones in water.

The growing interest in sonochemistry as a tool for environmental remediation leads to the need for process optimization. Sonochemistry is a complex process, which depends on physical parameters and also on the process conditions. Physical parameters are interrelated and therefore a systematic approach has to be taken to optimize the process.

Occurrence of estrogen hormones in biosolids, animal manure and mushroom compost.

The presence of natural estrogen hormones as trace concentrations in the environment has been reported by many researchers and is of growing concern due to its possible adverse effects on the ecosystem. In this study, municipal biosolids, poultry manure (PM) and cow manure (CM), and spent mushroom compost (SMC) were analyzed for the presence of seven estrogen hormones. 17α-estradiol, 17β-estradiol, 17α-dihydroequilin, and estrone were detected in the sampled biosolids and manures at concentrations ranging from 6 to 462 ng/g of dry solids.