Sulfonated cellulose nanocrystal modified with ammonium salt as reinforcement in poly(lactic acid) composite films.

Poly(lactic acid) (PLA) composites reinforced with cellulose nanocrystals (CNCs) are promising biodegradable materials. However, the poor compatibility and dispersion of CNCs in the PLA matrix remain a significant obstacle to improving the properties of composites. In this study, the modified CNC (CNC-D) was prepared through sulfonation treatment, followed by modification with didecyl dimethyl ammonium chloride (DDAC).

Fabrication of antimicrobial and high-toughness poly (lactic acid) composite films using tung oil derivatives.

Tung oil derivatives are promising alternatives to traditional toxic plasticizers for improving the toughness of poly (lactic acid) (PLA) films. In this study, a tung oil-based quaternary ammonium salt (Q-ETO) was synthesized using a multi-step process involving epoxidation, ring opening, and substitution reactions. PLA based composite films with various amounts of Q-ETO were prepared by solvent casting.