Femtosecond laser-induced nano- and microstructuring of Cu electrodes for CO electroreduction in acetonitrile medium.

The dependency of CO reduction rate in acetonitrile-BuNClO solution on cathodes, which were modified by laser induction of a copper surface, was studied. The topography of laser-induced periodic surface structures (LIPSS) → grooves → spikes was successively formed by a certain number of pulses. It was proved that for a higher number of laser pulses, the surface area of the copper cathode increases and preferred platy orientation of the copper surface on [022] crystallografic direction and larger fluence values increase.

Synthesis of silver nanoparticles by sonogalvanic replacement on aluminium powder in sodium polyacrylate solutions.

The process of the formation of silver nanoparticles (AgNPs) via the method of galvanic replacement (GR) of Ag with aluminum powder in sodium polyacrylate (NaPA) solutions in the ultrasonic (US) field has been studied. It was observed, that the yellow colloidal solutions of stabilized AgNPs with the absorption maximum at ∼ 410 nm were obtained under the application of US power by 20 W and frequency by 20 kHz in the wide range of AgNO and NaPA concentrations (0.1 - 0.

"Green" Synthesis of Metallic Nanoparticles by Sonoelectrochemical and Sonogalvanic Replacement Methods.

The main features of the "green" synthesis of metallic nanoparticles (MNPs) by the sonoelectrochemical methods are manufacturability, environmental friendliness, and the possibility of controlling the geometry of the forming particles. The electrochemical reduction technique allows efficiently designing the metal nanoparticles and provides the control of the content of components of bimetallic nanoparticles, as well as minimizing the number of precursors in working solutions. Due to the generation of turbulence, microjets, and shock waves, ultrasound increases mass transfer and formation of radicals in aqueous solutions and, accordingly, accelerates the processes of nucleation and growth of MNPs.