Method validation for simultaneous determination of four neonicotinoids in vegetables by liquid chromatography.

Pesticides are widely employed to boost the production of vegetable crops, but their indiscriminate application leaves residue in the crops for long, even after harvesting. Among pesticides, neonicotinoids are the most commonly applied group of insecticides which are used on vegetables to defend against a variety of sucking pests. The purpose of this study was to validate an analytical approach focused on QuEChERS extraction for the validation and simultaneous determination of residues of four neonicotinoids (imidacloprid, clothianidin, acetamiprid and thiamethoxam) in six diverse crops such as cucumber, brinjal, tomato, beans, cabbage, and cauliflower.

Method validation for determination of nine pesticides in okra and their mitigation using different solutions.

In this paper we optimized QuEChERS method for extraction of nine pesticides viz. acephate, acetamiprid, chlorpyrifos, cypermethrin, imidacloprid, thiamethoxam, profenofos (insecticides), carbendazim and tebuconazole (fungicides) and performed their quantitative estimation in okra crop by HPLC-UV and GC-ECD. Decontamination treatments namely washing with running tap water, soaking in lukewarm water (50-60°C), soaking in solutions of 1% NaCl, 5% NaHCO3, 2% CH3COOH, 0.