[Kinetic analysis of additive effect on desulfurization activity].

The additive effects of A12O3, Fe2O3 and MnCO3 on CaO sulfation kinetics were investigated by thermogravimetic analysis method and modified grain model. The activation energy (Ea) and the pre-exponential factor (k0) of surface reaction, the activation energy (Ep) and the pre-exponential factor (D0) of product layer diffusion reaction were calculated according to the model. Additions of MnCO3 can enhance the initial reaction rate, product layer diffusion and the final CaO conversion of sorbents, the effect mechanism of which is similar to that of Fe2O3.

[Factors of effects on transformation behaviors of inorganic mineral matters in desulfurizing process of burning coal].

The Heshan coal and the Wansheng coal were selected to investigate the effects of Ca/S molar ratio, combustion temperature and other factors on the desulfurization efficiency when limestone as a desulfurizer. And then the possible effects of various desufurizing systems on the mineral constituents of their residues were discussed by using the X-ray diffraction analyzer. Moreover, the phase diagrams of the ternary system CaO-Al2O3-SiO2 were further used in order to find out the transformation behaviors of inorganic mineral matters in the desulfurizing processes of burning coal on the basis of the XRD results.