Hydrothermal and thermal-alkali pretreatment potential was investigated to enhance agro-wastes' anaerobic co-digestion (AcoD). The techno-economic (TEA) and life cycle assessment (LCA) of biogas upgrading (BioCNG) and energy generation via combined heat and power (CHP) processes for energy utilization were carried out to realize the environmental impacts and cost-effectiveness of the studied processes. Three AcoD conditions of untreated, hydrothermally (150 °C, 60 min) and thermal-alkali pretreated (1% NaOH, 150 °C- 60 min) wheat straw (WS) with food waste and cow manure were studied in semi-continuous mode for 340 days under variable organic loading rates (OLR, 1.
View Article and Find Full Text PDFOccup Ther Health Care
April 2024
This paper describes an example of collaborative course development, in which occupational therapy faculty members designed a two-course sequence for teaching content related to occupational therapy with children and youth. They used a backward course design approach and performance-based learning objectives to create alignment between Accreditation Council for Occupational Therapy Education (ACOTE) standards, course assignments and instructional content. The authors present examples from their course design, along with evidence-based resources to guide educators working on developing new courses or revising existing courses.
View Article and Find Full Text PDFLithium-sulfur (Li-S) batteries have attracted much attention due to their superior theoretical specific capacity and high theoretical energy density. However, rapid capacity fading originating from the shuttle effect, insulating the S cathode and the dendrite formation on the Li anode restrict the practical applications of Li-S batteries. Herein, we suggest novel coatings on glass fiber separators to satisfy all high-performance Li-S battery requirements.
View Article and Find Full Text PDFBioelectrochemical systems (BESs) such as microbial fuel cells (MFCs) present numerous benefits for the removal and recovery of heavy metals from industrial and municipal wastewater. This study evaluated the life cycle environmental impact of simultaneous hexavalent chromium (Cr(vi)) removal and bioelectricity generation in a dual chamber MFC. Results indicate a global warming potential (GWP) of -0.
View Article and Find Full Text PDFSugarcane bagasse (SCB) is a significant agricultural residue generated by sugar mills based on sugarcane crop. Valorizing carbohydrate-rich SCB provides an opportunity to improve the profitability of sugar mills with simultaneous production of value-added chemicals, such as 2,3-butanediol (BDO). BDO is a prospective platform chemical with multitude of applications and huge derivative potential.
View Article and Find Full Text PDFJ Oral Maxillofac Pathol
February 2023
A 65-year-old female patient with a history of wearing a denture for 15 years reported with a complaint of pain in the floor of the mouth. On examination, a swelling measuring about 2.2 X1.
View Article and Find Full Text PDFBackground: Incarcerated individuals usually exhibit high oral health needs than the average population. Several factors contribute to these needs both before incarceration and during the sentence itself. Inmates are a marginalized group, who are at a higher risk for a variety of medical, dental, and emotional disorders than the general population.
View Article and Find Full Text PDFMicrobial electrosynthesis (MES), is an emerging technology, for sustainable wastewater treatment. The dilute acetate solution, produced via MES, must be recovered, as dilute solutions can be expensive to store and transport. The acetate is expensive and environmentally damaging to recover by heat-intensive evaporative methods, such as distillation.
View Article and Find Full Text PDFMicrobial electrosynthesis (MES) is an innovative technology for electricity driven microbial reduction of carbon dioxide (CO) to useful multi-carbon compounds. This study assesses the cradle-to-gate environmental burdens associated with acetic acid (AA) production MES using graphene functionalized carbon felt cathode. The analysis shows that, though the environmental impact for the production of the functionalized cathode is substantially higher when compared to carbon felt with no modification, the improved productivity of the process helps in reducing the overall impact.
View Article and Find Full Text PDFAccording to the US Department of Energy, succinic acid (SA) is a top platform chemical that can be produced from biomass. Bread waste, which has high starch content, is the second most wasted food in the UK and can serve as a potential low cost feedstock for the production of SA. This work evaluates the environmental performance of a proposed biorefinery concept for SA production by fermentation of waste bread using a cradle-to-factory gate life cycle assessment approach.
View Article and Find Full Text PDFInorganic scintillator-based gamma spectrometry is typically carried out under laboratory conditions by using systems that require AC mains supply and dedicated computers for their operation. In this study, an in-house grown CsI(Tl) single crystal scintillator is optically coupled to a bialkali photomultiplier tube (PMT). The output of the PMT is fed to a pulse processing chain consisting of a preamplifier followed by an in-house designed and developed field programmable gate array (FPGA) based multichannel analyzer (MCA).
View Article and Find Full Text PDFWe present a correlation for determining the power density of microbial fuel cells based on dimensional analysis. Important operational, design and biological parameters are non-dimensionalized using a selection of scaling variables. Experimental data from various microbial fuel cell studies operating over a wide range of system parameters are analyzed to attest accuracy of the model in predicting power output.
View Article and Find Full Text PDFFlame-retardant polyurethane foams are potential packing materials for the transport casks of highly active nuclear materials for shock absorption and insulation purposes. Exposure of high doses of gamma radiation causes cross-linking and chain sectioning of macromolecules in this polymer foam, which leads to reorganization of their cellular microstructure and thereby variations in physico-mechanical properties. In this study, in-house-developed flame-retardant rigid polyurethane foam samples were exposed to gamma irradiation doses in the 0-20 kGy range and synchrotron radiation X-ray micro-computed tomography (SR-µCT) imaging was employed for the analysis of radiation-induced morphological variations in their cellular microstructure.
View Article and Find Full Text PDFThis study describes and evaluates a dynamic computational model for a two chamber microbial electrosynthesis (MES) system. The analysis is based on redox mediators and a two population model, describing bioelectrochemical kinetics at both anode and cathode. Mass transfer rates of the substrate and bacteria in the two chambers are combined with the kinetics and Ohm's law to derive an expression for the cell current density.
View Article and Find Full Text PDFJ Synchrotron Radiat
September 2018
The Hard X-ray Photo-Electron Spectroscopy (HAXPES) beamline (PES-BL14), installed at the 1.5 T bending-magnet port at the Indian synchrotron (Indus-2), is now available to users. The beamline can be used for X-ray photo-emission electron spectroscopy measurements on solid samples.
View Article and Find Full Text PDFA novel framework, integrating dynamic simulation (DS), life cycle assessment (LCA) and techno-economic assessment (TEA) of a bioelectrochemical system (BES), has been developed to study for the first time wastewater treatment by removal of chemical oxygen demand (COD) by oxidation in anode and thereby harvesting electron and proton for carbon dioxide reduction reaction or reuse to produce products in cathode. Increases in initial COD and applied potential increase COD removal and production (in this case formic acid) rates. DS correlations are used in LCA and TEA for holistic performance analyses.
View Article and Find Full Text PDFPolymers (Basel)
October 2017
"Electrospinnability", or the ease with which a solution can be used to obtain bead-free uniform fibers, depends on a large number of parameters, including solution properties, process parameters and ambient conditions. In this study, the effect of the polymer relaxation time on electrospinning of dilute polymer solutions is investigated numerically. It is shown that elastic stresses (ES) increase exponentially with the Deborah number ( D e ).
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2017
Organic-inorganic nanocomposite self-standing films of GdGaAlO (GGAG) uniformly dispersed in poly(methyl methacrylate) (PMMA) and polystyrene polymer are prepared for radiography application. GGAG:Ce nanoscintillator has been chosen because of its high light output and fast decay time. The nanopowder of GGAG is synthesized by coprecipitation method and dispersed in the polymer matrix by a simple blending technique.
View Article and Find Full Text PDFPurpose: We sought to document the difference in the vitreoretinal configuration of Stage 4 retinopathy of prematurity (ROP) in photocoagulated and treatment naive eyes undergoing vitrectomy and to correlate it with surgical complexity.
Methods: Consecutive eyes posted for vitrectomy with Stage 4 ROP were documented preoperatively using a RetCam for the presence of peripheral traction (PT), presence of central traction just outside the arcades, and presence of traction extending to the lens. A note was made of the following intraoperative events: lensectomy, intraoperative bleeding, and iatrogenic breaks.
We developed a homogeneous bridging anti-drug antibody (ADA) assay on an electro chemiluminescent immunoassay (ECLIA) platform to support the immunogenicity evaluation of a dimeric domain antibody (dAb) therapeutic in clinical studies. During method development we evaluated the impact of different types of acid at various pH levels on polyclonal and monoclonal ADA controls of differing affinities and on/off rates. The data shows for the first time that acids of different pH can have a differential effect on ADA of various affinities and this in turn impacts assay sensitivity and drug tolerance as defined by these surrogate controls.
View Article and Find Full Text PDFAvailability of microfocus X-ray sources and high resolution X-ray area detectors has made it possible for high resolution microtomography studies to be performed outside the purview of synchrotron. In this paper, we present the work towards the use of an external shutter on a high resolution microtomography system using X-ray CCD camera as a detector. During micro computed tomography experiments, the X-ray source is continuously ON and owing to the readout mechanism of the CCD detector electronics, the detector registers photons reaching it during the read-out period too.
View Article and Find Full Text PDFPurpose: The purpose of this study was to evaluate functional and anatomical outcomes of posterior iris-claw intraocular lens (IOL) implant for correction of aphakia in eyes with inadequate capsular support.
Materials And Methods: Prospective case series of 108 aphakic eyes with inadequate capsular support which underwent posterior iris-claw IOL with a 6-month follow-up period was conducted. The cases belonged to two clinical settings: elective secondary implantation and those with intraoperative posterior dislocation of cataractous lens or IOL.