Various chemical and surface analysis techniques, including Raman and X-ray photoelectron spectroscopy, are used to study how adding As(V) affects the biooxidation of arsenopyrite by a bacterium called Acidithiobacillus thiooxidans.
The findings suggest that arsenic enhances bacterial activity during bioleaching, which impacts how arsenic moves in the environment and leads to changes in biofilm characteristics.
Results show significant differences in surface reactivity and secondary compound formation in the presence of As(V), along with a shift in biofilm properties from hydrophilic to hydrophobic despite a reduction in extracellular surface proteins.