The distorted square-planar coordination environment of the palladium(II) centre in [Pd(NCN)I].2I(2) [NCN is 2,6-bis[(dimethylamino)methyl]phenyl, C(12)H(19)N(2)] is defined by the monoanionic terdentate NCN ligand and one iodide anion. Two neutral I(2) molecules interact with the coordinated iodide anion at distances of approximately 3.
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