Single-atom-based Metal-Organic Frameworks (MOFs) hold great promising candidates for heterogeneous catalysis, demonstrating outstanding catalytic activity and exceptional product selectivity. This is attributed to their optimal atom utilization, high surface energy, and the presence of unsaturated coordination environments. Here in, we have developed a nickel single-atom catalyst (UiO-66/Ni) featuring Ni single atoms covalently attached to defect-engineered Zr-oxide clusters within the stable UiO-66 framework, synthesized via a straightforward solution impregnation method.
View Article and Find Full Text PDFBackground Low back pain (LBP) is the leading cause of disability among working-age adults, with its prevalence increasing with age and peaking in the 45-54 age group. It is common practice for clinicians to conduct advanced imaging procedures, such as computed tomography (CT) and magnetic resonance imaging (MRI) when a patient presents with LBP. The objective of this study was to measure and analyze the width of the ligamentum flavum (LF) on each side and the extent of degeneration of the disc at the L3-4, L4-5, and L5-S1 levels.
View Article and Find Full Text PDFTightly confined plasmons in metal nanogaps are highly sensitive to surface inhomogeneities and defects due to the nanoscale optical confinement, but tracking and monitoring their location is hard. Here, we probe a 1-D extended nanocavity using a plasmonic silver nanowire (AgNW) on mirror geometry. Morphological changes inside the nanocavity are induced locally using optical excitation and probed locally through simultaneous measurements of surface enhanced Raman scattering (SERS) and dark-field spectroscopy.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Severe burns pose significant threats to patient well-being, characterized by pain, inflammation, bacterial infection, and extended recovery periods. While exosome-loaded hydrogels have demonstrated considerable promise in wound healing, current formulations often fall short of achieving optimal therapeutic efficacy for burn wounds due to challenges related to their adaptability to wound shape and limited anti-bacterial capabilities. In this study a novel exosome laden sprayable thermosensitive polysaccharide-based hydrogel (ADA-aPF127@LL18/Exo) comprising alginate dialdehyde (ADA) and aminated Pluronic F127 (aPF127) was fabricated via Schiff base reaction.
View Article and Find Full Text PDFBiological soil amendments of animal origin (BSAAO) are a source of foodborne pathogens that can contaminate fresh produce. This study evaluated the survival of E. coli over 140 d in agricultural soils amended with composted poultry litter (PL), heat-treated poultry pellets (HTPP), or unamended (UN) in Florida (FL) and Georgia (GA).
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