Quantum Dot Light-Emitting Devices: Beyond Alignment of Energy Levels.

Multinary semiconductor nanoparticles such as CuInS, AgInS, and the corresponding alloys with ZnS hold promise for designing future quantum dot light-emitting devices (QLED). The QLED architectures require matching of energy levels between the different electron and hole transport layers. In addition to energy level alignment, conductivity and charge transfer interactions within these layers determine the overall efficiency of QLED.

Optical and Electronic Properties of Nonconcentric PbSe/CdSe Colloidal Quantum Dots.

Lead chalcogenide colloidal quantum dots are attractive candidates for applications operating in the near infrared spectral range. However, their function is forestalled by limited stability under ambient conditions. Prolonged temperature-activated cation-exchange of Cd(2+) for Pb(2+) forms PbSe/CdSe core/shell heterostructures, unveiling a promising surface passivation route and a method to modify the dots' electronic properties.

PbSe-Based Colloidal Core/Shell Heterostructures for Optoelectronic Applications.

Lead-based (IV-VI) colloidal quantum dots (QDs) are of widespread scientific and technological interest owing to their size-tunable band-gap energy in the near-infrared optical region. This article reviews the synthesis of PbSe-based heterostructures and their structural and optical investigations at various temperatures. The review focuses on the structures consisting of a PbSe core coated with a PbSeS (0 ≤ ≤ 1) or CdSe shell.

Full spectral and angular characterization of highly directional emission from nanocrystal quantum dots positioned on circular plasmonic lenses.

We design a circular plasmonic lens for collimation of light emission from nanocrystal quantum dots at room temperature in the near IR spectral range. We implement a two-dimensional k-space imaging technique to obtain the full spectral-angular response of the surface plasmon resonance modes of the bare plasmonic lens. This method is also used to map the full spectral-angular emission from nanocrystal quantum dots positioned at the center of the circular plasmonic lens.