Both the global and European energy sectors have been undergoing a deep transition for several years, associated with a reduction in the overall share of conventional coal-based energy in favor of new technologies, especially energy from renewable sources (RES). This transition is moving from centralized production towards distributed technologies and from providing only energy to end users towards combining innovative products and services with it. Electricity consumers are becoming prosumers connected to the grid and generating an increasing amount of energy.
View Article and Find Full Text PDFSingle-atom-based Metal-Organic Frameworks (MOFs) hold great promising candidates for heterogeneous catalysis, demonstrating outstanding catalytic activity and exceptional product selectivity. This is attributed to their optimal atom utilization, high surface energy, and the presence of unsaturated coordination environments. Here in, we have developed a nickel single-atom catalyst (UiO-66/Ni) featuring Ni single atoms covalently attached to defect-engineered Zr-oxide clusters within the stable UiO-66 framework, synthesized via a straightforward solution impregnation method.
View Article and Find Full Text PDFBackground Low back pain (LBP) is the leading cause of disability among working-age adults, with its prevalence increasing with age and peaking in the 45-54 age group. It is common practice for clinicians to conduct advanced imaging procedures, such as computed tomography (CT) and magnetic resonance imaging (MRI) when a patient presents with LBP. The objective of this study was to measure and analyze the width of the ligamentum flavum (LF) on each side and the extent of degeneration of the disc at the L3-4, L4-5, and L5-S1 levels.
View Article and Find Full Text PDFTightly confined plasmons in metal nanogaps are highly sensitive to surface inhomogeneities and defects due to the nanoscale optical confinement, but tracking and monitoring their location is hard. Here, we probe a 1-D extended nanocavity using a plasmonic silver nanowire (AgNW) on mirror geometry. Morphological changes inside the nanocavity are induced locally using optical excitation and probed locally through simultaneous measurements of surface enhanced Raman scattering (SERS) and dark-field spectroscopy.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Severe burns pose significant threats to patient well-being, characterized by pain, inflammation, bacterial infection, and extended recovery periods. While exosome-loaded hydrogels have demonstrated considerable promise in wound healing, current formulations often fall short of achieving optimal therapeutic efficacy for burn wounds due to challenges related to their adaptability to wound shape and limited anti-bacterial capabilities. In this study a novel exosome laden sprayable thermosensitive polysaccharide-based hydrogel (ADA-aPF127@LL18/Exo) comprising alginate dialdehyde (ADA) and aminated Pluronic F127 (aPF127) was fabricated via Schiff base reaction.
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