Design and Application of a Gas Diffusion Electrode (GDE) Cell for Operando and In Situ Studies.

Presented here is an electrochemical three-electrode Gas Diffusion Electrode (GDE) cell tailored for operandoand in situ investigations of electrocatalytic processes, with a particular focus on X-ray scattering studies. The optimized cell is engineered to accommodate the minimal sample-detector distances requisite for comprehensive X-ray total scattering investigations. An in-depth understanding of catalytic processes requires their study under 'working' conditions.

Nanocomposite Concept for Electrochemical Preparation of Pt-Au Alloy Nanoparticles for Formic Acid Oxidation.

Herein, we report a straightforward approach for the preparation of Pt-Au alloy nanoparticles from Pt + Au/C nanocomposites using monometallic colloidal nanoparticles as starting blocks. Four different compositions with fixed Pt content and varying Pt to Au mass ratios from 1:1 up to 1:7 were prepared as formic acid oxidation reaction (FAOR) catalysts. The study was carried out in a gas diffusion electrode (GDE) setup.

The Gas Diffusion Electrode Setup as Straightforward Testing Device for Proton Exchange Membrane Water Electrolyzer Catalysts.

Hydrogen production from renewable resources and its reconversion into electricity are two important pillars toward a more sustainable energy use. The efficiency and viability of these technologies heavily rely on active and stable electrocatalysts. Basic research to develop superior electrocatalysts is commonly performed in conventional electrochemical setups such as a rotating disk electrode (RDE) configuration or H-type electrochemical cells.

Testing a Silver Nanowire Catalyst for the Selective CO₂ Reduction in a Gas Diffusion Electrode Half-cell Setup Enabling High Mass Transport Conditions.

In this work, we discuss the application of a gas diffusion electrode (GDE) setup for benchmarking electrocatalysts for the reductive conversion of CO₂ (CO₂ RR: CO₂ reduction reaction). Applying a silver nanowire (Ag-NW) based catalyst, it is demonstrated that in the GDE setup conditions can be reached, which are relevant for the industrial conversion of CO₂ to CO. This reaction is part of the so-called 'Rheticus' process that uses the CO for the subsequent production of butanol and hexanol based on a fermentation approach.