Publications by authors named "G Rogez"

A rigid pentadentate chelating ligand (HL) has been utilized to synthesize a series of octacoordinate mononuclear complexes, [Dy(L)(PhPO)(OOCR)] (where R = CH (1), C(CH) (2), CF (3)) and a dinuclear complex, [Dy(L)(PhPO){(OOC)CH}] (4) based on the highly anisotropic Dy(III) ion. All the complexes were structurally characterized by single-crystal X-ray diffraction studies. The complexes were formed by the coordination action of the dianionic pentadentate ligand [L], one phosphine oxide, and carboxylate ligands.

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Natural language plays a critical role in many computer vision applications, such as image captioning, visual question answering, and cross-modal retrieval, to provide fine-grained semantic information. Unfortunately, while human pose is key to human understanding, current 3D human pose datasets lack detailed language descriptions. To address this issue, we have introduced the PoseScript dataset.

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In search of new multifunctional hybrid materials and in order to investigate the influence of chemical modification on the possible synergy between properties, the carboxylate and sulfonate derivatives of photo- and thermochromic N-salicylidene aniline were successfully inserted into Co(II)- and Zn(II)-based layered simple hydroxides, resulting in four novel hybrids: Co--Sali-COO, Co--Sali-SO, Zn--Sali-COO, and Zn--Sali-SO. All synthesized hybrids adopt a double organic layered configuration, which prevents the photoisomerization ability of -Sali-R molecules in the hybrids. However, the Zn hybrids exhibit fluorescence upon exposure to UV light due to the excited-state intramolecular proton transfer (ESIPT) mechanism.

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Article Synopsis
  • Four new metallophosphonates were synthesized using a hydrothermal method from thianthrene-2-ylphosphonic acid, resulting in unique structures characterized by a lamellar configuration of inorganic and organic networks.
  • The compounds display significant thermal stability and were analyzed for their thermal properties using thermogravimetric analysis, confirming the presence of water molecules in their formulae.
  • Magnetic studies revealed dominant antiferromagnetic interactions in the materials at varying temperatures, with further insights provided by first-principles simulations, and the optical properties showed distinct absorption and emission behaviors influenced by the organic component and transition metals.
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Training state-of-the-art models for human pose estimation in videos requires datasets with annotations that are really hard and expensive to obtain. Although transformers have been recently utilized for body pose sequence modeling, related methods rely on pseudo-ground truth to augment the currently limited training data available for learning such models. In this paper, we introduce PoseBERT, a transformer module that is fully trained on 3D Motion Capture (MoCap) data via masked modeling.

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