Occurrence and behaviour of colloidal silica and silica-rich nanoparticles through stages of reverse osmosis treating coal seam gas associated water.

Reverse Osmosis (RO) membrane filtration is a very common process for treating a wide range of groundwater types including produced water from coal seam gas (coalbed methane) wells. Mineral scaling limits water recovery for RO membranes and costs money in terms of treatment and downtime. Silica scaling can be particularly troublesome as it is often irreversible.

Silica fouling during groundwater RO treatment: The effect of colloids' radius of curvature on dissolution and polymerisation.

Silica fouling during groundwater reverse osmosis (RO) treatment can have a significant impact on filtration performance. To better understand this phenomenon, the equilibrium kinetics of amorphous colloidal silica were studied at conditions relevant to RO of silica-rich alkaline groundwater. The impact of particle size was investigated using synthetic monodisperse silica nanoparticles.

Capacitance of Nanoporous Carbon-Based Supercapacitors Is a Trade-Off between the Concentration and the Separability of the Ions.

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid electrolytes, should in principle yield larger capacitances. Here, we show by using electrochemical measurements that the capacitance is not significantly affected when switching from a pure ionic liquid to a conventional organic electrolyte using the same ionic species.

Mixed Matrix Carbon Molecular Sieve and Alumina (CMS-Al2O3) Membranes.

This work shows mixed matrix inorganic membranes prepared by the vacuum-assisted impregnation method, where phenolic resin precursors filled the pore of α-alumina substrates. Upon carbonisation, the phenolic resin decomposed into several fragments derived from the backbone of the resin matrix. The final stages of decomposition (>650 °C) led to a formation of carbon molecular sieve (CMS) structures, reaching the lowest average pore sizes of ~5 Å at carbonisation temperatures of 700 °C.

Downstream processing of reverse osmosis brine: Characterisation of potential scaling compounds.

Reverse osmosis (RO) brine produced at a full-scale coal seam gas (CSG) water treatment facility was characterized with spectroscopic and other analytical techniques. A number of potential scalants including silica, calcium, magnesium, sulphates and carbonates, all of which were present in dissolved and non-dissolved forms, were characterized. The presence of spherical particles with a size range of 10-1000 nm and aggregates of 1-10 microns was confirmed by transmission electron microscopy (TEM).