The optoelectronic properties of polythiophene (PT) graft block copolymers are most important for fabricating optoelectronic devices, and recently, we reported a single-pot atom-transfer radical polymerization (ATRP) technique for preparation of PT graft block copolymers between thermoresponsive poly(diethylene glycol methyl ether methacrylate) (PDEGMEM) and pH-responsive poly(dimethyl amino ethyl methacrylate) (PDMAEMA) from the PT backbone via the "" strategy with an 11 mol % contamination. A "" strategy has been opted to eliminate the contamination from the block copolymer where we synthesized poly(thiophene acetic acid) (P3TAA) followed by the coupling with PDEGMEM--PDMAEMA-Cl, PDMAEMA--PDEGMEM-Cl, and PDMAEMA--PDEGMEM-Cl copolymers, produced separately by the ATRP technique. The polymers were characterized using H NMR, SEC, etc.
View Article and Find Full Text PDFNoxious effect on environmental due to carbon emissions is being addressed worldwide by governments through carbon pricing instruments. Two of prevalent instruments adopted by governments are simple carbon tax and cap-and-trade policy. Effectiveness of carbon pricing instruments towards achieving reduction in carbon emissions is a matter of study on one hand.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2022