Acta Crystallogr E Crystallogr Commun
September 2024
The title compound, [Sn(CH)Cl(CHN)], which was obtained by the reaction between 1,10-phenanthroline and phenyl-tin trichloride in methanol, exhibits intra-molecular hydrogen-bonding inter-actions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by inter-molecular C-H⋯Cl hydrogen bonds, as well as -⋯π and π-stacking inter-actions involving three different aromatic rings with centroid-centroid distances of 3.6605 (13), 3.
View Article and Find Full Text PDFIn the hydrated title salt, (CHNO)[SnCl]·2HO, the tin(IV) atom is located about a center of inversion. In the crystal structure, the organic cation, the octa-hedral inorganic anion and the water mol-ecule of crystallization inter-act through O-H⋯O, N-H⋯O and O-H⋯Cl hydrogen bonds, supplemented by weak π-π stacking between neighboring cations, and C-Cl⋯π inter-actions.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
August 2020
In the title mol-ecular salt, (CHN)[SnCl], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H⋯Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions.
View Article and Find Full Text PDFRendering in virtual reality (VR) requires substantial computational power to generate 90 frames per second at high resolution with good-quality antialiasing. The video data sent to a VR headset requires high bandwidth, achievable only on dedicated links. In this paper we explain how rendering requirements and transmission bandwidth can be reduced using a conceptually simple technique that integrates well with existing rendering pipelines.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
January 2016
The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2] n , comprises one Co(II) atom, one water mol-ecule, one singly deprotonated malonic acid mol-ecule (HMal(-); systematic name 2-carb-oxy-acetate) and one Cl(-) anion. The Co(II) atom is octa-hedrally coordinated by the O atom of a water mol-ecule, by one terminally bound carboxyl-ate O atom of an HMal(-) anion and by two O atoms of a chelating HMal(-) anion, as well as by two Cl(-) anions. The Cl(-) anions bridge two Co(II) atoms, forming a centrosymmetric Co2Cl2 core.
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