Encapsulated Atomic Hydrogen in Octamethyl-POSS Cages: A Pulsed EPR Study.

Encapsulated atomic hydrogen in polyhedral oligomeric silsesquioxane (POSS) cages is a promising candidate for spin-based quantum technologies. Key parameters such as spin relaxation times and magnetic interactions with surrounding electron and nuclear spins can be typically probed with advanced electron paramagnetic resonance (EPR) methods. Here we present a detailed pulsed EPR study of the species H@SiOR with R=CH, namely encapsulated atomic hydrogen in the octamethyl POSS derivative.

Aggregation-Driven Photoinduced α-C(sp)-H Bond Hydroxylation/C(sp)-C(sp) Coupling of Boron Dipyrromethene Dye in Water Reported by Near-Infrared Emission.

Molecular aggregation is a powerful tool for tuning advanced materials' photophysical and electronic properties. Here we present a novel potential for the aqueous-solvated aggregated state of boron dipyrromethene (BODIPY) to facilitate phototransformations otherwise achievable only under harsh chemical conditions. We show that the photoinduced symmetry-breaking charge separation state can itself initiate catalyst-free redox chemistry, leading to selective α-C(sp)-H bond activation/C-C coupling on the BODIPY backbone.

Heme Spin Distribution in the Substrate-Free and Inhibited Novel CYP116B5hd: A Multifrequency Hyperfine Sublevel Correlation (HYSCORE) Study.

The cytochrome P450 family consists of ubiquitous monooxygenases with the potential to perform a wide variety of catalytic applications. Among the members of this family, CYP116B5hd shows a very prominent resistance to peracid damage, a property that makes it a promising tool for fine chemical synthesis using the peroxide shunt. In this meticulous study, we use hyperfine spectroscopy with a multifrequency approach (X- and Q-band) to characterize in detail the electronic structure of the heme iron of CYP116B5hd in the resting state, which provides structural details about its active site.

Long Electron Spin Coherence Times of Atomic Hydrogen Trapped in Silsesquioxane Cages.

Encapsulated atomic hydrogen in cube-shaped octasilsesquioxane (POSS) cages of the SiOR type (where R is an organic group) is one of the simplest alternative stable systems to paramagnetic endofullerenes that have been regarded as key elements of spin-based quantum technologies. Apart from common sources of decoherence such as nuclear spin and spectral diffusion, all H@POSS species studied so far suffer from additional shortening of at low temperatures due to methyl group rotations. Here we eliminate this factor for the first time by studying the smallest methyl-free derivative with R = H, namely, H@TH.

Photocatalytic degradation of organic micropollutants under UV-A and visible light irradiation by exfoliated g-CN catalysts.

In the present study, the photocatalytic performance of exfoliated graphitic carbon nitride (g-CN) catalysts, with enhanced properties and response in UV and visible light irradiation, was evaluated for the removal of selected contaminants i.e., diuron, bisphenol A and ethyl paraben.