Tertiary/quaternary treatment of urban wastewater by UV/HO or ozonation: Microplastics may affect removal of E. coli and contaminants of emerging concern.

The aim of this study was to investigate the interference of polyethylene microplastics (MPs) on ultraviolet irradiation/hydrogen peroxide (UV/HO) and ozonation processes in the inactivation of E. coli bacteria (tertiary treatment) and removal of contaminants of emerging concern (CECs) (quaternary treatment) from simulated and real secondary treated urban wastewater. Three pharmaceuticals were investigated as model CECs, namely carbamazepine, sulfamethoxazole and trimethoprim.

Simultaneous disinfection and microcontaminants elimination of urban wastewater secondary effluent by solar advanced oxidation sequential treatment at pilot scale.

The effect of different times of Fe:Ethylenediamine-N, N'-disuccinic acid (EDDS) dosing and HO as well as different Fe:EDDS concentrations in the sequential treatment sunlight/HO followed by sunlight/HOFe:EDDS at circumneutral pH was investigated for the first time focusing both in contaminants of emerging concern (CECs) and bacteria removal in urban wastewater treatment plant effluents. Process efficiency was evaluated in terms of (i) degradation of five CECs (namely caffeine, carbamazepine, diclofenac, sulfamethoxazole and trimethoprim) at the initial concentration of 100 μgL each and (ii) bacteria inactivation (Escherichia coli (E. coli) and Salmonella spp).

Sunlight advanced oxidation processes vs ozonation for wastewater disinfection and safe reclamation.

Solar processes (sunlight/HO solar photo-Fenton with EDDS at neutral pH) were compared to a consolidated technology (ozonation) in the inactivation of target bacteria (E. coli, Salmonella spp. and Enterococcus spp.

Simultaneous removal of contaminants of emerging concern and pathogens from urban wastewater by homogeneous solar driven advanced oxidation processes.

Simultaneous removal of contaminants of emerging concern and bacteria inactivation in simulated municipal wastewater effluent (SMWW) through solar advanced oxidation processes, namely sunlight/HO and solar photo-Fenton with Ethylenediamine-N,N'-disuccinic acid (EDDS) at neutral pH was investigated. Process efficiency was evaluated in terms of (i) degradation of five contaminants of emerging concern (CECs, namely caffeine, carbamazepine, diclofenac, sulfamethoxazole and trimethoprim) at the initial concentration of 100 μgL each and (ii) bacteria inactivation (E. coli, S.

Removal of carbamazepine, diclofenac and trimethoprim by solar driven advanced oxidation processes in a compound triangular collector based reactor: A comparison between homogeneous and heterogeneous processes.

Contaminants of emerging concern (including pharmaceuticals) are not effectively removed by municipal wastewater treatment plants (WWTPs), so particular concern is related to agricultural wastewater reuse due to their possible uptake in crops irrigated with WWTPs effluents. Advanced oxidation processes (AOPs) and solar AOPs have been demonstrated to effectively remove pharmaceuticals from different aqueous matrices. In this study, an heterogeneous photocatalytic process using powdered nitrogen-doped TiO immobilized on polystyrene spheres (sunlight/N-TiO) was compared to the benchmark homogenous AOP sunlight/HO in a compound triangular collector reactor, to evaluate the degradation of three pharmaceuticals (carbamazepine (CBZ), diclofenac (DCF), trimethoprim (TMP)) in water.