Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1'-Dimethyl-2,2'-bibenzimidazole: Influence of Structure on Photophysics.

A reaction of a cyclic trinuclear copper(I) or silver(I) pyrazolate complex ([MPz], M = Cu, Ag) with 1,1'-dimethyl-2,2'-bibenzimidazole () leads to the formation of tetranuclear adducts decorated by one or two molecules of a diimine ligand, depending on the amount of the ligand added (0.75 or 1.5 equivalents).

Study of the Structure and Properties of Electrical Sand Concrete under Prolonged Exposure to Sulfate Environment.

Destructive processes accompanying sulfate corrosion of concrete significantly affect the durability of products and structures based on Portland cement. In the presented study, the long-term effect of sulfate corrosion on the electrical properties of electrically conductive sand concrete was studied. In the course of the study, the following were tested: an electrically conductive composition and a control composition based on plain Portland cement.

Impact of Carbon Particle Character on the Cement-Based Composite Electrical Resistivity.

Electroconductive cement-based composites are modern materials that are commonly used in many industries such as the construction industry, among others. For example, these materials can be used as sensors for monitoring changes in construction, grounding suspension, and resistance heating materials, etc. The aim of the research presented in this article is to monitor the impact of carbon particle character on cement-based electroconductive composites.

Rainfall Intensity and Quantity Estimation Method Based on Gamma-Dose Rate Monitoring.

The features of the atmospheric γ-background reaction to liquid atmospheric precipitation in the form of bursts is investigated, and various forms of them are analyzed. A method is described for interpreting forms of the measured γ-background response with the determination of the beginning and ending time of precipitation, the distinctive features of changes in the intensity of precipitation and the number of single (separate) events that form one burst. It is revealed that a change in the intensity of precipitation in one event leads to a change in the γ-radiation dose rate increase speed (time derivative).

The Effect of Complex Modification on the Impedance of Cement Matrices.

The research results presented in this article were obtained by joint scientific research on creatingcement materials with reduced impedance. It is known that functional additives added to impart electrically conductive properties have a negative impact on physical and mechanical characteristics of the material. This study suggests using the multiwall carbon nanotubes in the amount of 7% from binder mass as a functional additive.