Corrosion of Heritage Objects: Collagen-Like Triple Helix Found in the Calcium Acetate Hemihydrate Crystal Structure.

Helical motifs are common in nature, for example, the DNA double or the collagen triple helix. In the latter proteins, the helical motif originates from glycine, the smallest amino acid, whose molecular confirmation is closely related to acetic acid. The combination of acetic acid with calcium and water, which are also omnipresent in nature, materializing as calcium acetate hemihydrate, was now revealed to exhibit a collagen-like triple helix structure.

A hydrated crystalline calcium carbonate phase: Calcium carbonate hemihydrate.

As one of the most abundant materials in the world, calcium carbonate, CaCO, is the main constituent of the skeletons and shells of various marine organisms. It is used in the cement industry and plays a crucial role in the global carbon cycle and formation of sedimentary rocks. For more than a century, only three polymorphs of pure CaCO-calcite, aragonite, and vaterite-were known to exist at ambient conditions, as well as two hydrated crystal phases, monohydrocalcite (CaCO·1HO) and ikaite (CaCO·6HO).

Colloidal aggregates of Pd nanoparticles supported by larch arabinogalactan.

Palladium nanoparticles (PdNPs) are used in catalysis, hydrogen storage, biomedicine, and so on. Arranging the self-assembly of PdNPs within colloidal aggregates is desirable for improving their consumer properties. Stable widely dispersed colloidal aggregates of larch arabinogalactan (LARB) containing nanosized (5-nm) PdNPs were obtained by reducing Pd ions in alkaline solutions of LARB.