Clicked into Place: Biomimetic Copolymer Adhesive for Covalent Conjugation of Functionalities.

Polydopamines (PDA) are a popular class of materials and promising candidates as adhesives for new fastening techniques. PDA layers can be formed on a wide range of substrates in various environments. Here, we present a novel method for functionalizing PDA-based copolymer films by using click chemistry.

Strongly Inhibited Spontaneous Emission of PbS Quantum Dots Covalently Bound to 3D Silicon Photonic Band Gap Crystals.

We present an optical study of the spontaneous emission of lead sulfide (PbS) nanocrystal quantum dots in 3D photonic band gap crystals made from silicon. The nanocrystals emit in the near-infrared range to be compatible with 3D silicon nanophotonics. The nanocrystals are covalently bound to polymer brush layers that are grafted from the Si-air interfaces inside the nanostructure by using surface-initiated atom transfer radical polymerization.

Aptamer Clicked Poly(ferrocenylsilanes) at Au Nanoparticles as Platforms with Multiple Function.

Aptamers are widely used in biosensing due to their specific sensitivity toward many targets. Thus, gold nanoparticle (AuNP) aptasensors are subject to intense research due to the complementary properties of aptamers as sensing elements and AuNPs as transducers. We present herein a novel method for the functional coupling of thrombin-specific aptamers to AuNPs via an anionic, redox-active poly(ferrocenylsilane) (PFS) polyelectroyte.

Suppression of the Coffee Ring Effect in a Single Solvent-Based Silicon Nanoparticle Ink.

Silicon (Si) is made printable by dispersing Si nanoparticles in a single organic solvent. Viscoelastic properties of the prepared inks as well as the uniformity of inkjet-printed thin films are investigated in dependence on the Si volume fraction. It has been demonstrated that no ink additives are needed to completely suppress the occurrence of the coffee ring effect.

Engineering of Adhesion at Metal-Poly(lactic acid) Interfaces by Poly(dopamine): The Effect of the Annealing Temperature.

Control over adhesion at interfaces from strong bonding to release between thermoplastic polymers (TPs) and metal oxides is highly significant for polymer composites. In this work, we showcase a simple and inexpensive method to tune adhesion between a TP of growing interest, poly(lactic acid) (PLA), and two commercial metal alloys, based on titanium and stainless steel. This is realized by coating titanium and stainless steel wires with polydopamine (PDA), thermally treating them under vacuum at temperatures ranging from 25 to 250 °C, and then comolding them with PLA to form pullout specimens for adhesion tests.