Mathematical models of transesterification commonly assume that oil is a mixture of triacylglycerols, where each component has only one type of acid attached. This article aims to show how a different assumption on acid distribution affects the results of acylglycerols fraction composition. Experiments of fish oil ethanolysis have been performed at different enzyme loadings and ethanol concentrations, leading to enrichments from 35 % to 52 % of ω3 mass fraction in acylglycerols, by losing 12.
View Article and Find Full Text PDFIn the pathway towards decarbonization, hydrogen can provide valid support in different sectors, such as transportation, iron and steel industries, and domestic heating, concurrently reducing air pollution. Thanks to its versatility, hydrogen can be produced in different ways, among which steam reforming of natural gas is still the most commonly used method. Today, less than 0.
View Article and Find Full Text PDFEnviron Res
January 2023
The carbonation of alkaline wastes is an interesting research field that may offer opportunities for CO reduction. However, the literature is mainly devoted to studying different waste sequestration capabilities, with lame attention to the reliability of the data about CO reduction, or to the possibilities to increase the amount of absorbed CO. In this work, for the first time, the limitation of some methods used in literature to quantify the amount of sequestered CO is presented, and the advantages of using suitable XRD strategies to evaluate the crystalline calcium carbonate phases are demonstrated.
View Article and Find Full Text PDFThis paper investigates the influence of the support material and its thickness on the hydrogen flux in Palladium membranes in the presence of sweep gas in fluidized bed membrane reactors. The analysis is performed considering both ceramic and metallic supports with different properties. In general, ceramic supports are cheaper but suffer sealing problems, while metallic ones are more expensive but with much less sealing problems.
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