Application of TLC for confirmation and screening of pesticide residues in fruits, vegetables, and cereal grains: Part 2. Repeatability and reproducibility of Rf and MDQ values.

This paper illustrates the effect of major factors influencing the reproducibility of thin layer chromatography (TLC) separation and detection under largely differing environmental and laboratory conditions. The optimum conditions for reproducibility and detection sensitivity was obtained on 20 x 20 cm layer in the retention factor (Rf) range of 0.2-0.

A cost-effective screening method for pesticide residue analysis in fruits, vegetables, and cereal grains.

This paper reports the results of studies performed to investigate the potential of applying thin layer chromatography (TLC) detection in combination with selected extraction and cleanup methods, for providing an alternative cost-effective analytical procedure for screening and confirmation of pesticide residues in plant commodities. The extraction was carried out with ethyl acetate and an on-line extraction method applying an acetone-dichloromethane mixture. The extracts were cleaned up with SX-3 gel, an adsorbent mixture of active carbon, magnesia, and diatomaceous earth, and on silica micro cartridges.

Teratogenicity testing of BI 58 EC (38% dimethoate) in chicken embryos with special respect to degradation of the active ingredient.

The insecticide formulation BI 58 EC was tested for teratogenicity in chicken embryos, with particular reference to degradation of the active ingredient (dimethoate) after the treatment of embryonated eggs. The pesticide was diluted in water to a concentration level of 0.8%, and the emulsion was injected into the air space in a volume of 0.

Measurements of surface contamination of spray equipment with pesticides after various methods of application.

A traditional method to determine operator dermal exposure is to quantify the amount of pesticide coming into contact with specific body regions and then to integrate the deposition density values with the total body surface. It is known that extremely high deposition values may occur in the hand region; however, the source of contamination is generally assumed to be direct splash or contact with the pesticide container. One of the parameters affecting operator/pilot exposure could be the transfer of pesticide residue, particularly in the case of pesticides with a longer half-life, from contaminated surfaces of spray equipment by direct contact over extended periods.

Characteristics of applicator exposure to synthetic pyrethroid in ULV-handheld and ULV-ULA spray applications.

The technique of ultra-low volume by ultra-light aircraft for pesticide spray application has been discussed for some time in North America, mainly due to the air worthiness of such an aircraft which was not designed to carry appreciable amounts of payload. The risk factor of such application in insect control has not been determined, while applicator exposure to insecticide in ULV application by manual sprayer was assessed. An attempt was made to produce, by a series of field exposure measurements, a set of applicator exposure data for ULV-ULA and to compare the results with the data produced in synthetic pyrethroid application by using a hand-held ULV applicator.

Occupational exposure to organophosphorus insecticides and synthetic pyrethroid.

Dermal and respiratory exposure to pirimiphosmethyl, dimethoate and permethrin were determined for applicators and operators in greenhouse tomato spraying operations. Dermal exposure is several times higher than the degree of respiratory exposure. Dermal exposure in terms of different parts of the body shows significant differences.