The main bottleneck of rechargeable aqueous zinc batteries (AZBs) is their limited cycle lifespans stemming from the unhealthy electrolyte bulk and fragile interface, especially in the absence of dynamic protection mechanism between them. To overcome this limitation, benefitting from their synergistic physical and chemical properties, chitin nanocrystals (ChNCs) are employed as superior colloid electrolyte to bridge electrolyte bulk and interfacial chemistry for ultra-long lifespan AZBs. This unique strategy not only enables continuous optimization of the electrolyte bulk and interfacial chemistry within the battery but also facilitates self-repairing of mechanical damage both internally and externally, thereby achieving comprehensive, persistent, and dynamic protection.
View Article and Find Full Text PDFFlexible and high-performance aqueous zinc-ion batteries (ZIBs), coupled with low cost and safe, are considered as one of the most promising energy storage candidates for wearable electronics. Hydrogel electrolytes present a compelling alternative to liquid electrolytes due to their remarkable flexibility and clear advantages in mitigating parasitic side reactions. However, hydrogel electrolytes suffer from poor mechanical properties and interfacial chemistry, which limits them to suppressed performance levels in flexible ZIBs, especially under harsh mechanical strains.
View Article and Find Full Text PDFThe design of aqueous zinc (Zn) chemistry energy storage with high rate-capability and long serving life is a great challenge due to its inhospitable coordination environment and dismal interfacial chemistry. To bridge this big gap, herein, we build a highly reversible aqueous Zn battery by taking advantages of the biomass-derived cellulose nanocrystals (CNCs) electrolyte additive with unique physical and chemical characteristics simultaneously. The CNCs additive not only serves as fast ion carriers for enhancing Zn transport kinetics but regulates the coordination environment and interface chemistry to form dynamic and self-repairing protective interphase, resulting in building ultra-stable Zn anodes under extreme conditions.
View Article and Find Full Text PDFSpin polarization of two-dimensional electron gas (2DEG) at the interface of EuTiO/SrTiO(STO) heterostructures has been theoretical predicted and experimentally observed via x-ray magnetic circular dichroism and polarized x-ray absorption spectroscopy, which, however, is lack of magnetotransport evidence. Here, we report the fabrication of high-quality EuTiO/STO heterostructures by depositing antiferromagnetic insulating EuTiOthin films onto STO substrates. Shubnikov-de Haas oscillation, Hall, and magnetoresistance (MR) measurements show that the interface is not only highly conducting, with electron mobility up to5.
View Article and Find Full Text PDFCorrection for 'Magnetotransport and magnetic properties of Cr-modified MnSb epitaxial thin films' by Ting-Wei Chen , , 2023, , 5785-5794, https://doi.org/10.1039/D2CP05442F.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2023
High-quality MnCrSb ( = 0.01, 0.04, and 0.
View Article and Find Full Text PDFTo realize the predictive control of coal preparation quality and ensure that the quality of washing products is close to the minimum coal quality requirement of coal blending to the greatest extent is one of the important means to maximize production and maintain the interests of customers and enterprises. Therefore, the feasibility of introducing the double response surface method and multiobjective genetic algorithm to solve the aforementioned problems is further discussed. By selecting the controllable factors and noise factors affecting the output and determining their respective value levels, the product table method is used to design the robust parameter design test, and the experimental results are obtained, according to the experimental data, the second-order polynomial model of the mean and standard deviation of each response characteristic is established, and the effectiveness of the model is analyzed.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2021
Stoichiometric CrSe single crystals are particular layer-structured antiferromagnets, which possess a noncollinear spin configuration, weak ferromagnetic moments, moderate magnetoresistance (MR ∼14.3%), and poor metallic conductivity below the antiferromagnetic phase transition. Here, we report an interesting >16 000% colossal magnetoresistance (CMR) effect in Ti (1.
View Article and Find Full Text PDFMar Pollut Bull
November 2021
In this paper, a marine environmental sensitivity index system was constructed based on three factors: the marine biological species sensitivity, the marine ecological value sensitivity and the social and economic sensitivity. Combined with numerical simulations of Cs in the Beibu Gulf under the condition of a level-7 nuclear accident, a comprehensive risk assessment of marine radioactivity under the simulated accident in the Beibu Gulf was carried out. The results show that the areas at high risk and medium-to-high risk to marine radioactivity are mainly concentrated within 30 km of the Fangchenggang Nuclear Power Plant.
View Article and Find Full Text PDFBackground: A motivation dimension of the core psychiatric symptom anhedonia additional has been suggested. The Temporal Experience of Pleasure Scale (TEPS) has been reported to assess anticipatory and consummatory pleasure separately in multiple factor-structure models. This study explored the factor structure of a Chinese version of the 18-item TEPS and further explored the measurement invariance of the TEPS across sex and clinical status (non-clinical, psychiatric).
View Article and Find Full Text PDFThe Personality Inventory for the DSM-5 (PID-5) is an established tool for assessing personality disorder (PD) traits that was developed based on section III of the DSM-5. It is composed of 220 items, organized into 25 facets, which are distributed among five domains. The psychometric properties of the Chinese version of the PID-5 remain to be demonstrated.
View Article and Find Full Text PDFBackground: The Personality Inventory for DSM-5 Brief Form (PID-5-BF) is a 25-item measuring tool evaluating maladaptive personality traits for the diagnosis of personality disorders(PDs). As a promising scale, its impressive psychometric properties have been verified in some countries, however, there have been no studies about the utility of the PID-5-BF in Chinese settings. The current study aimed to explore the maladaptive personality factor model which was culturally adapted to China and to examine psychometric properties of the PID-5-BF among Chinese undergraduate students and clinical patients.
View Article and Find Full Text PDFBackground: Anhedonia, a key symptom of depression and schizophrenia, has emerged as a potential endophenotype. The aim of this study was to evaluate the psychometric properties of a Chinese version of the Snaith-Hamilton Pleasure Scale(SHAPS), a self-report anhedonia scale, in a non-clinical sample and clinical sample inclusive of major depressive disorder (MDD), schizophrenia, or a personality disorder.
Methods: A total of 4,722 undergraduate students and 352 clinical patients participated in this study.
Background: Anhedonia is a core clinical symptom of mental disorders. The Revised Physical Anhedonia Scale (RPAS) and the Revised Social Anhedonia Scale (RSAS) have been applied in clinical and non-clinical samples since 1980s. However, the construct of a unified RPAS&RSAS for comprehensive measurement of anhedonia has never been explored.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2008
The luminescence properties of four europium chelates with increasing benzene ring substituents ligand in poly(methylmethacrylate) (PMMA) have been investigated by fluorescence emission spectra and lifetime measurements. According to the fluorescence emission spectra, the Judd-Ofelt parameters Omega2, Omega4 of europium chelates-doped PMMA have been calculated and the radiative properties were also presented. It showed that the increase of benzene ring substituents in ligand can increase the metastable state lifetime tau(m), the luminescence quantum yield eta and the stimulated emission cross-section sigma of 5D0-->7F2 transition.
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