Any experimental Thermoluminescent (TL) glow-peak contains the activation energy information of its corresponding energy level within the band gap in insulating materials. The theory of peak shape methods (PSM) correlates the macroscopic geometrical characteristics of a single TL peak with activation energy of the level responsible for the TL peak by assuming that the area under a TL peak can be approximated by the area of a triangle. In this way the geometrical characteristics becomes the measure of the activation energy.
View Article and Find Full Text PDFHalf-life is one of the fundamental parameters to characterize the thermoluminescent (TL) response in ionizing radiation dosimetry. In general, there are two types of important half-lives to model the phenomenon of thermoluminescence (TL). The first type of half-life is the time required for the concentration of trapped charge carriers in a single trap to decrease to half its initial value; this type of half-life is generally denoted as τ.
View Article and Find Full Text PDFThis paper presents the results of a long experimental work carried out to study the influence of the heating rate (H.R.) on thermally stimulated light emission phenomenon, well known as thermoluminescence (TL) of MgBO activated by Tm and Dy ions (MgBO:Tm.
View Article and Find Full Text PDFAppl Radiat Isot
November 2016
The characterization of new materials thermoluminescent used in radiation dosimetry, require the determination of kinetic parameters, which are associated with the number and shape of the peaks which presents its glow curve, among the most important are: the activation energy, E, or depth of the traps, the frequency factor, s, and the kinetics order, b. These parameters are necessary to predict the stability of thermoluminescent information after irradiation of the material. In this work, we present the results obtained for the determination of kinetic parameters of Tm-doped CaF, the methods used for the determination of kinetic parameters were; initial growth signal TL, General order Chen method, and Deconvolution of glow curve.
View Article and Find Full Text PDFImported commercial samples of Yerba Mate (Ilex paraguariensis) tea leaves were characterized by thermoluminescence (TL) and photoluminescence (PSL) physical methods. Samples of Yerba Mate were irradiated between 0.5-50Gy and 20Gy-5kGy gamma doses by using two different dose rates from (60)Co irradiators.
View Article and Find Full Text PDFThe isothermal decay method is useful for determining the trap activation energy in thermoluminescent material for dosimetry purposes. Recently we proposed new modified expressions for isothermal decay method. As validation of the modified expressions, after long-term (4 h) high temperature storage, the activation energy of experimental TL glow peaks, KMgF3:Lu (0.
View Article and Find Full Text PDFWe report the effect of thermal treatment on thermoluminescent (TL) sensitivity property of CaSO4:Dy obtained by a new preparation method at Instituto Nacional de Investigaciones Nucleares (ININ) of Mexico. Samples of phosphor powder were subjected to different thermal treatments respectively at 773, 873, 973 and 1,173K for 1h and then irradiated from 0.1 to 1,000 Gy gamma doses.
View Article and Find Full Text PDFThe perovskite-like LiMgF(3):ErF(3) pellets were obtained from the melt formed by LiF and MgF(2) mixed salts in the stoichiometric ratio. The perovskite material was doped with 1, 2 and 4 mol% of ErF(3) impurity. The pellets samples were (60)Co gamma irradiated and their thermoluminescence (TL) properties were analyzed, i.
View Article and Find Full Text PDFAppl Radiat Isot
October 2011
The influence of heating rate on the thermoluminescence (TL) property of LiF:Mg,Cu,P+PTFE was analyzed. The activation energy and the frequency factor as a function of the heating rate were determined. The kinetic parameters and their dependence on the heating rate were evaluated using the sequential quadratic programming glow curve deconvolution (SQPGCD).
View Article and Find Full Text PDFAppl Radiat Isot
February 2011
The thermoluminescent response and kinetics parameters of NaCl, doubly activated by Ca-Mn and Cd-Mn ions, exposed to gamma radiation are analyzed. The doped NaCl samples were irradiated at relative low temperature, i.e.
View Article and Find Full Text PDFThis paper gives a full mathematical description of the kinetics expressions used in thermoluminescent isothermal decay experiments. The corresponding equations have been slightly modified considering the peak intensity at the maximum (I(M)) instead of the peak area Φ as proportional to absorbed dose, given normally in isothermal decay equations. The isothermal decay method was applied to the principal glow peaks of two different phosphors: LiF:Mg,Cu,P+PTFE, using first- and second-order kinetics, and BaSO(4):Eu+PTFE, using second-order kinetics.
View Article and Find Full Text PDFAppl Radiat Isot
February 2011
The well known Initial Rise Method (IR) is commonly used to determine the activation energy when only one glow peak is presented and analysed in the phosphor materials. However, when the glow peak is more complex, a wide peak and some holders appear in the structure. The application of the Initial Rise Method is not valid because multiple trapping levels are considered and then the thermoluminescent analysis becomes difficult to perform.
View Article and Find Full Text PDFThis work describes an algorithm for absorbed dose evaluation in the region of X-ray diagnostic energy based on the response of CaSO(4):Dy thermoluminescence powder detectors. The absorbed dose was calculated using Monte Carlo simulation code (MCSC) and then compared to the experimental TLD results for X-rays effective energies (60)Co gamma radiation. In order to study the photon interaction in the matter, a cylindrical model of 1 cm(3) was used.
View Article and Find Full Text PDFThe aim of this work is to present the results concerning the photon irradiation of a new phosphor, the LiF:Mg,Cu,P+PTFE, produced at the Instituto Nacional de Investigaciones Nucleares (ININ-Mexico). The photon irradiations were performed using X-rays of 16, 24, 34.5, 42, 100 and 145keV, and gamma rays from (137)Cs (662keV) and from (60)Co (1 252keV).
View Article and Find Full Text PDFRadiat Prot Dosimetry
December 2006
The parameters characterising the trap centres involved in the thermoluminescence of KMgF3:LaF3 compounds have been found by deconvolving the glow curve with the General One Trap model (GOT). For the fitting procedure the Levenberg-Marquardt method has been employed. Tm-T(stop) measurements along with initial rise measurements were performed in order to estimate the number of peaks the glow curve is made up of, and the corresponding activation energies.
View Article and Find Full Text PDFRadiat Prot Dosimetry
December 2006
Numerical solutions of the differential equations system describing the transitions between energy levels can help in the understanding of the physical mechanisms governing thermoluminescence (TL) emission but they are not suitable for the analysis of complex experimental TL glow curves. On the other hand, simplified descriptions, as mixed or general order kinetics, require many additional assumptions that may limit the validity of the results or are mostly empirical. In this paper, the accuracy of such approximations has been evaluated for different retrapping-recombination ratios and it has been found that differences between the fitted and the simulated parameters arise from the simplification of the models because quasi-equilibrium condition seems to be valid in all the considered cases.
View Article and Find Full Text PDFThe thermoluminescence properties of the inorganic dust extracted from the Chile Guajillo (paprika) Mexicano, were studied in order to verify the possibility of using the TL technique to discriminate between irradiated and non irradiated peppers. The inorganic dust was found to consist of quartz 60%, albite (NaAlSi(3)O(8)) 30%, and ortose (KAlSi(3)O(8)) 10%. Its thermoluminescence dose response covers the wide dose range of 1 Gy--10 kGy, which was attributed mainly to feldspars.
View Article and Find Full Text PDFThe main dosimetric properties are reported of a new perovskite, LiMgF3, doped with Ce, Er and Dy impurities. An annealing temperature of 400 degrees C for one hour is necessary to erase any previous signal and to stabilise its sensitivity. A readout up to 450 degrees C gives the same result.
View Article and Find Full Text PDFRadiat Prot Dosimetry
April 2003
The potentialities of optically stimulated luminescence (OSL) for personal dosimetry of ionising radiation have stimulated the search for new synthetic materials with good dosimetric properties. The sensitivity of two new OSL materials KMgF3 and NaMgF3 doped with Ce3+ ions has been evaluated and found to be of the same order of magnitude as that of Al2O3:C. Several other characteristics have also been investigated.
View Article and Find Full Text PDFAppl Radiat Isot
October 2001
The perovskites are very interesting for their thermoluminescent properties and for their possible application as thermoluminescent dosimeters (TLD). In this paper we present results concerning the main dosimetric properties of KMgF3 activated by Ce and Er at various concentrations, i.e.
View Article and Find Full Text PDFThis paper presents the dosimetric results obtained during computed tomography (CT) thorax examinations, carried out using two different techniques, i.e., sequential CT (SQCT) and helical CT (HECT).
View Article and Find Full Text PDFAppl Radiat Isot
February 2000
Thermoluminescent dosimetric characteristics of MgB4O7:Dy,Na are presented. MgB4O7:Dy,Na is a newly prepared TL material with attractive features for dosimetric applications, such as near-tissue equivalence, simple glow curve, high sensitivity and low fading. The dosimetric properties of this material examined in this study include glow curve shape, TL sensitivity, annealing procedure, photon dose response, minimum detectable dose, precision of TL measurements, reproducibility, energy response and fading characteristics.
View Article and Find Full Text PDFLiF: Mg, Cu, P is a TL material presenting unique dosimetric features. The TL sensitivity of this material was studied as a function of the annealing temperature and of the repeated cycles of annealing-irradiation-readout. A fading study was carried out over a period of 40 days with the purpose of checking the stability of the stored dosimetric information as a function of different annealing temperatures.
View Article and Find Full Text PDFThe neologism "hadrontherapy" means radiotherapy with hadrons, which are the particles constituted by quarks, such as protons, neutrons and ions. The theoretical considerations about the clinical advantages this treatment modality can yield and the results obtained at the centers where it has already been used justify the proposal to project a center of this kind also in our Country. To this purpose, two of the authors of this paper (U.
View Article and Find Full Text PDFInt J Rad Appl Instrum A
March 1988
Information about the time that has elapsed since an external radiation exposure is useful in order to determine the time of occurrence of an abnormal exposure in personal and accidental dosimetry is presented. This information can be obtained from certain irradiated thermoluminescent dosimeters. A computational method based on decay rates of thermoluminescence glow peaks has been used to estimate a range of suitable values of trap lifetimes of low temperature glow peaks.
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