[Characteristic of 8p11 Myeloproliferative Syndrome with Rare Phenotype].

Objective: To deeply understand the clinical manifestation, laboratory examination characteristics, diagnosis and treatment of an eight p11 myeloproliferative syndrome (EMS) with rare phenotypes.

Methods: The clinical and laboratory characteristics and the process of allogeneic hematopoietic stem cell transplantation (allo-HSCT) were summarized in 1 rare EMS case involving T/B/myeloid cells. Meanwhile, 2 similar cases in the previous literature were also discussed.

A 2D bilayered metal-organic framework as a fluorescent sensor for highly selective sensing of nitro explosives.

A novel Cd-MOF (metal organic framework) [Cd3(NTB)2(DMA)3]·2DMA (H3NTB = 4,4',4''-nitrilotrisbenzoic acid; DMA = N,N-dimethylacetamide) () was obtained under solvothermal conditions. The resulting MOF exhibits a novel (2D→3D) interdigitated architecture that is obtained from a bilayered motif with hexagonal grids. Luminescence properties of the activated phase of well dispersed in different solvents have also been investigated systematically, which demonstrate distinct solvent-dependent luminescence spectra with emission intensities significantly quenched toward nitrobenzene (NB) and 2,4,6-trinitrophenol (TNP).

Pillared metal organic frameworks for the luminescence sensing of small molecules and metal ions in aqueous solutions.

Two novel pillared MOFs (metal organic frameworks) [Zn2(trz)2(tda)]·DMA CH3OH (1) and [Zn2(trz)2(bpdc)]·DMA (2) were obtained under solvothermal conditions. The resulting MOFs show similar structures but with different interlayer distances based on the different carboxylate ligands. 1 and 2 display a certain degree of framework stability in both acid/base solutions and water.

Redox-controlled δ-Dawson {Mn2(III)W17} polyoxometalate with photocatalytic H2 evolution activity.

A novel δ-Dawson [(WO5)3W14Mn2(III)O44Cl2](12-) compound induced by the Jahn-Teller distortion of Mn(III) has been synthesized through utilizing {Mn12} as a reactant, which exhibits photocatalytic H2 evolution activity. Its electrochemical behavior and magnetic properties were investigated.

5,6-Dimethyl-pyrazine-2,3-dicarb-oxy-lic acid.

The asymmetric unit of the title compound, C(8)H(8)N(2)O(4), consists of one complete mol-ecule and a second mol-ecule generated by the application of twofold axis. The mean planes of the two carboxyl groups attached to the pyrazine ring at neighboring positions are twisted by 10.8 (1) and 87.

Poly[[μ(7)-l-cysteato(2-)]disodium].

The title compound {systematic name: poly[[μ(7)-(2R)-2-amino-3-sulfonato-propano-ato]disodium]}, [Na(2)(C(3)H(5)NO(5)S)](n), was obtained through solvent-thermal reaction of l-cysteic acid and aqueous sodium hydroxide. The monomer consists of two Na(+) cations that are coordinated to the deprotonated amino acid. The latter acts as donor utilizing all available coordination sites, viz.