GdO:1% Er, 18% Yb,% Mg( = 0; 2.5; 4; 5; 6; 8;10; 20; 25; 50) and GdO:1% Er, 18% Yb, 2,5% Mg,% Li( = 0.5-2.
View Article and Find Full Text PDFIn this work we adapt rare-earth-ion-doped NaYFnanoparticles coated with a silicon oxide shell (NaYF:20%Yb,0.2%Tm@SiO) for biological and medical applications (for example, imaging of cancer cells and therapy at the nano level). The wide upconversion emission range under 980 nm excitation allows one to use the nanoparticles for cancer cell (4T1) photodynamic therapy (PDT) without a photosensitizer.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
March 2020
Magnetic nanoparticles of FeO doped by different amounts of Y (0, 0.1, 1, and 10%) ions were designed to obtain maximum heating efficiency in magnetic hyperthermia for cancer treatment. Single-phase formation was evident by X-ray diffraction measurements.
View Article and Find Full Text PDFNanostructures as color-tunable luminescent markers have become major, promising tools for bioimaging and biosensing. In this paper separated molybdate/GdO doped rare earth ions (erbium, Er and ytterbium, Yb) core-shell nanoparticles (NPs), were fabricated by a one-step homogeneous precipitation process. Emission properties were studied by cathodo- and photoluminescence.
View Article and Find Full Text PDFElectropolymerizable functional and cross-linking monomers were used to prepare conducting molecularly imprinted polymer film with improved surface area with the help of a sacrificial metal-organic framework (MOF). Subsequent dissolution of the MOF layer resulted in a surface developed MIP film. This surface enlargement increased the analyte accessibility to imprinted molecular cavities.
View Article and Find Full Text PDFThis study describes a new method of passivating ZnO nanofiber-based devices with a ZnS layer. This one-step process was carried out in H2S gas at room temperature, and resulted in the formation of core/shell ZnO/ZnS nanofibers. This study presents the structural, optical and electrical properties of ZnO/ZnS nanofibers formed by a 2 nm ZnS sphalerite crystal shell covering a 5 nm ZnO wurtzite crystal core.
View Article and Find Full Text PDFA novel recognition unit of chemical sensor for selective determination of the inosine, renal disfunction biomarker, was devised and prepared. For that purpose, inosine-templated molecularly imprinted polymer (MIP) film was deposited on an extended-gate field-effect transistor (EG-FET) signal transducing unit. The MIP film was prepared by electrochemical polymerization of bis(bithiophene) derivatives bearing cytosine and boronic acid substituents, in the presence of the inosine template and a thiophene cross-linker.
View Article and Find Full Text PDFAn effective, simple and practically useful method to incorporate fluorescent nanoparticles inside live biological cells was developed. The internalization time and concentration dependence of a frequently used liposomal transfection factor (Lipofectamine 2000) was studied. A user friendly, one-step technique to obtain water and organic solvent soluble Er(3+) and Yb(3+) doped NaYF4 nanoparticles coated with polyvinylpyrrolidone was obtained.
View Article and Find Full Text PDFA facile sol-gel synthesis of novel ZnO/MgO/Fe2O3 nanoparticles (NPs) is reported and their performance is compared to that of ZnO/MgO. Powder x-ray diffraction (XRD) patterns reveal the crystal structure of the prepared samples. The average particle size of the sample was found to be 4.
View Article and Find Full Text PDFThis report presents the results of spectroscopic measurements of colloidal ZnO nanoparticles synthesized in various alcohols. Luminescence of colloidal ZnO was monitored under different reaction conditions to elucidate the mechanism of the visible emission. We performed the process in different alcohols, temperatures and reaction times for two different reactants: water and NaOH.
View Article and Find Full Text PDFWe fabricated a hybrid structure in which cobalt and permalloy micromagnets produce a local in-plane spin-dependent potential barrier for high-mobility electrons at the GaAs/AlGaAs interface. Spin effects are observed in ballistic transport in the range of tens of mT of the external field and are attributed to switching between Zeeman and Stern-Gerlach modes--the former dominating at low electron densities.
View Article and Find Full Text PDFPhys Rev B Condens Matter
October 1991