An exchange-Coulomb model potential energy surface for the Ne-CO interaction. II. Molecular beam scattering and bulk gas phenomena in Ne-CO mixtures.

Four potential energy surfaces are of current interest for the Ne-CO interaction. Two are high-level fully ab initio surfaces obtained a decade ago using symmetry-adapted perturbation theory and supermolecule coupled-cluster methods. The other two are very recent exchange-Coulomb (XC) model potential energy surfaces constructed by using ab initio Heitler-London interaction energies and literature long range dispersion and induction energies, followed by the determination of a small number of adjustable parameters to reproduce a selected subset of pure rotational transition frequencies for the (20)Ne-(12)C(16)O van der Waals cluster.

Predicted bound states and microwave spectrum of N2-He van der Waals complexes.

Numerical calculations show that four modern potential energy surfaces for N(2)-He all support 18 bound intermolecular states for the homonuclear isotopologues (14,14)N(2)-(4)He and (15,15)N(2)-(4)He, and 12 (or 13, for one surface) truly bound states for (14,15)N(2)-He. This contradicts a recent statement [Patel et al., J.

An exchange-Coulomb model potential energy surface for the Ne-CO interaction. I. Calculation of Ne-CO van der Waals spectra.

Exchange-Coulomb model potential energy surfaces have been developed for the Ne-CO interaction. The initial model is a three-dimensional potential energy surface based upon computed Heitler-London interaction energies and literature results for the long-range induction and dispersion energies, all as functions of interspecies distance, the orientation of CO relative to the interspecies axis, and the bond length of the CO molecule. Both a rigid-rotor model potential energy surface, obtained by setting the CO bond length equal to its experimental spectroscopic equilibrium value, and a vibrationally averaged model potential energy surface, obtained by averaging the stretching dependence over the ground vibrational motion of the CO molecule, have been constructed from the full data set.

Accuracy of recent potential energy surfaces for the He-N2 interaction. II. Molecular beam scattering and bulk gas relaxation phenomena.

A new semiempirical exchange-Coulomb model potential energy surface for the N(2)-He interaction was reported recently [A. K. Dham et al.

Accuracy of recent potential energy surfaces for the He-N2 interaction. I. Virial and bulk transport coefficients.

A new exchange-Coulomb semiempirical model potential energy surface for the He-N2 interaction has been developed. Together with two recent high-level ab initio potential energy surfaces, it has been tested for the reliability of its predictions of second-virial coefficients and bulk transport phenomena in binary mixtures of He and N2. The agreement with the relevant available measurements is generally within experimental uncertainty for the exchange-Coulomb surface and the ab initio surface of Patel et al.

New exchange-Coulomb N2-Ar potential-energy surface and its comparison with other recent N2-Ar potential-energy surfaces.

The reliability of five N2-Ar potential-energy surfaces in representing the N2-Ar interaction has been investigated by comparing their abilities to reproduce a variety of experimental results, including interaction second viral coefficients, bulk transport properties, relaxation phenomena, differential scattering cross sections, and the microwave and infrared spectra of the van der Waals complexes. Four of the surfaces are the result of high-level ab initio quantal calculations; one of them utilized fine tuning by fitting to microwave data. To date, these four potential-energy surfaces have only been tested against experimental microwave data.

Experimental and theoretical study of proton spin-lattice relaxation in H2-Ar gas mixtures: critical examination of the XC(fit) potential energy surface.

Proton nuclear magnetic resonance spin-lattice relaxation time measurements have been carried out at 500 MHz proton Larmor frequency on two hydrogen-argon gas mixtures with 1.90% and 3.93% hydrogen at four different temperatures in the range 225 K < T < 337 K and at two different number densities.