Thickness Variation of Conductive Polymer Coatings on Si Anodes for the Improved Cycling Stability in Full Pouch Cells.

Si-dominant anodes for Li-ion batteries provide very high gravimetric and volumetric capacity but suffer from low cycling stability due to an unstable solid electrolyte interphase (SEI). In this work, we improved the cycling performance of Si/NCM pouch cells by coating the Si anodes with the conductive polymer poly(3,4-ethylenedioxythiophene) (PEDOT) prior to cell assembly via an electropolymerization process. The thicknesses of the PEDOT coatings could be adjusted by a facile process parameter variation.

GD-OES Investigations of Lithium-Ion Battery Graphite Anodes: Impact of Plasma Parameters and Electrode Properties.

Due to the demand of lithium-ion battery investigations with glow discharge optical emission spectroscopy (GD-OES), a fundamental study of the influence of essential GD-OES parameters toward graphite anodes in an argon plasma was conducted and compared to previous investigations of massive materials. It is shown that increased applied voltage (500-700 V) enhances the sputtering rate by up to 100%/100 V while keeping the crater shape unaffected. In contrast to this, gas pressure variation seems to be the main tool for crater shape adjustment.

-Block metal complexes with bis(pyrazol-1-yl)acetato ligands.

The hetereoscorpionate ligands bis(pyrazol-1-yl)acetic acid (Hbpza) and bis(3,5-dimethylpyrazol-1-yl)acetic acid (Hbdmpza) are reacted with [Sn(OAc)] or [Sn(acac)] to yield the corresponding Sn(II) complexes. A single crystal X-ray determination for the in solution monomeric complex [Sn(bpza)] (1a) revealed a dinuclear molecular structure [Sn(bpza)] (1b), with κ-N,N,O-coordinated bpza ligands at each of the Sn(II) and two bpza ligands μ-bridging between the Sn(II) centres. The molecular structure of [Sn(bdmpza)] (2) exhibits a homoleptic bisligand complex with both ligands displaced by the free electron pair, which is proven by DFT calculations.