Spectrochim Acta A Mol Biomol Spectrosc
November 2024
Breath analysis enables rapid, noninvasive diagnosis of human health by identifying and quantifying exhaled biomarker. Here, we demonstrated an exhaled breath sensing method using the near-infrared laser spectroscopy, and sub parts-per-million (ppm) level ammonia detection inside the exhaled gas was achieved employing a distributed feedback laser centered at 1512 nm and Kalman filtering algorithm. Integration of the ammonia sensor was realized for exhaled breath analysis of kidney patients, and a dual operation mechanism with static and dynamic modes was proposed to make this method applicable for real-time and comprehensive pre-diagnosis of kidney disease.
View Article and Find Full Text PDFCavity-enhanced direct frequency comb spectroscopy (CE-DFCS) is widely used as a highly sensitive gas sensing technology in various gas detection fields. For the on-axis coupling incidence scheme, the detection accuracy and stability are seriously affected by the cavity-mode noise, and therefore, stable operation inevitably requires external electronic mode-locking and sweeping devices, substantially increasing system complexity. To address this issue, we propose off-axis cavity-enhanced optical frequency comb spectroscopy from both theoretical and experimental aspects, which is applied to the detection of single- and dual-gas of carbon monoxide (CO) and carbon dioxide (CO) in the near-infrared.
View Article and Find Full Text PDFCompared to the most commonly used on-chip direct absorption spectroscopy (DAS) gas detection technique, the second harmonic (2f) based on-chip wavelength modulation spectroscopy (WMS) proposed by our group has the faculty to suppress noise and improve performance, but the accuracy of 2f WMS is easily affected by optical power variation. A mid-infrared auto-correction on-chip gas sensor based on 2f/1f WMS was proposed for decreasing the influence of the variation of optical power. The limit of detection of methane (CH) obtained by a chalcogenide waveguide with a length of 10 mm is 0.
View Article and Find Full Text PDFFolded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy (FO-QEPA-PTS) is reported for the first time. In FO-QEPA-PTS, the detection of the photoacoustic and photothermal hybrid signal is achieved through the use of a custom quartz tuning fork (QTF), thereby mitigating the issue of resonant frequency mismatch typically encountered in quartz-enhanced photoacoustic-photothermal spectroscopy employing multiple QTFs. A multi-laser beam, created by a multi-pass cell (MPC) with a designed single-line spot pattern, partially strikes the inner edge of the QTF and partially passes through the prong of the QTF, thereby generating photoacoustic and photothermal hybrid signals.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2024
On-chip waveguide sensors are potential candidates for deep-space exploration because of their high integration and low power consumption. Since the fundamental absorption of most gas molecules exists in the mid-infrared (e.g.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2023
SU8 is a cost-effective polymer material that is highly suitable for large-scale fabrication of waveguides. However, it has not been employed for on-chip gas measurement utilizing infrared absorption spectroscopy. In this study, we propose a near-infrared on-chip acetylene (CH) sensor using SU8 polymer spiral waveguides for the first time to our knowledge.
View Article and Find Full Text PDFTo realize early fire identification in cotton harvesting operations, a mid-infrared carbon monoxide (CO) sensor system was developed. To match the broadband light source with a 15° divergence angle, a multipass gas cell (MPGC) with an effective path length of 180 cm was designed to improve sensor sensitivity, leading to a limit of detection (LoD) of 0.83 parts-per-million by volume (ppmv).
View Article and Find Full Text PDFPortable or even on-chip detection of methane (CH) is significant for environmental protection and production safety. However, optical sensing systems are usually based on discrete optical elements, which makes them unsuitable for the occasions with high portability requirement. In this work, we report on-chip silicon-on-insulator (SOI) waveguide CH sensors at 3.
View Article and Find Full Text PDFA vehicle-deployed parts-per-billion in volume (ppbv)-level off-axis integrated cavity output spectroscopic (OA-ICOS) CH/CH sensor system was experimentally presented for mobile inspection of natural gas leakage in urban areas. For the time-division-multiplexing-based dual-gas sensor system, an antivibration 35-cm-long optical cavity with an effective path length of ∼2510 m was fabricated with a high-stability temperature and pressure control design. An Allan deviation analysis yielded a minimum detection limit of 0.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
April 2022
In order to realize early fire detection and location, a mid-infrared carbon monoxide (CO) and carbon dioxide (CO) dual-gas sensor system was developed, which mainly includes a gas pretreatment module, a CO sensor module, a CO sensor module, and a laptop monitoring platform. CO and CO absorption lines located at 4.26 μm and 4.
View Article and Find Full Text PDFIn SF insulated high-voltage gas power systems, HO is the most problematic impurity which not only decreases insulation performance but also creates an acidic atmosphere that promotes corrosion. Corrosion damages electrical equipment and leads to leaks, which pose serious safety hazards to people and the environment. A QEPAS-based sensor system for the sub-ppm level HO detection in SF buffer gas was developed by use of a near-infrared commercial DFB diode laser.
View Article and Find Full Text PDFA ppb-level HS and CO photoacoustic spectroscopy (PAS) gas sensor was developed by using a two-stage commercial optical fiber amplifier with a full output power of 10 W. Two near-infrared diode lasers with the central wavenumbers of 6320.6 cm and 6377.
View Article and Find Full Text PDFThis publisher's note contains corrections to Opt. Lett.46, 4797 (2021)OPLEDP0146-959210.
View Article and Find Full Text PDFA trace gas sensing technique of light-induced off-axis cavity-enhanced thermoelastic spectroscopy (OA-CETES) in the near-infrared was demonstrated by combing a high-finesse off-axis integrated cavity and a high Q-factor resonant quartz tuning fork (QTF). Sensor parameters of the cavity and QTF were optimized numerically and experimentally. As a proof-of-principle, we employed the OA-CETES for water vapor (HO) detection using a QTF (Q-factor ∼12000 in atmospheric pressure) and a 10cm-long Fabry-Perot cavity (finesse ∼ 482).
View Article and Find Full Text PDFA novel, to the best of our knowledge, mid-infrared chalcogenide (ChG) on magnesium fluoride () waveguide gas sensor was fabricated by using the lift-off method. was used as a lower cladding layer to increase the external confinement factor for enhancing light-gas interaction. Wavelength modulation spectroscopy (WMS) was used in carbon dioxide () detection at the wavelength of 4319 nm (2315.
View Article and Find Full Text PDFRadial-cavity quartz-enhanced photoacoustic spectroscopy (RC-QEPAS) was proposed for trace gas analysis. A radial cavity with (0,0,1) resonance mode was coupled with the quartz tuning fork (QTF) to greatly enhance the QEPAS signal and facilitate the optical alignment. The coupled resonance enhancement effects of the radial cavity and QTF were analyzed theoretically and researched experimentally.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
July 2021
We demonstrated a novel multi-input multi-output (MIMO) laser-to-cavity coupling scheme in off-axis integrated cavity output spectroscopy (OA-ICOS) for cavity mode noise suppression. Theoretical investigation was performed to explore the relation between the number of splitting beams and the MIMO parameters. Mode distribution and propagation inside the cavity was simulated.
View Article and Find Full Text PDFA multi-pass quartz-enhanced photoacoustic spectroscopy (MP-QEPAS)-based trace gas sensor is reported. In MP-QEPAS, a multi-pass laser beam pattern through the prong spacing of a quartz tuning fork (QTF) is obtained by means of two right-angle prisms. A large QTF with the prong length of 17 mm and prong spacing of 0.
View Article and Find Full Text PDFA wavelength-locked light-induced thermo-elastic spectroscopy (WL-LITES) gas sensor system was proposed for long-distance in-situ methane (CH) detection using a fiber-coupled sensing probe. The wavelength-locked scheme was used to speed the sensor response without scanning the laser wavelength across the CH absorption line. A small-size piezoelectric quartz tuning fork (QTF) with a wide spectral response range was adopted to enhance the photo-thermal signal.
View Article and Find Full Text PDFA near-infrared methane (CH) sensor system for carbon isotopic abundance analysis was developed based on laser absorption spectroscopy (LAS). For good thermal stability, two CH absorption lines with a similar low-state energy level were selected to realize relative weak temperature dependence. Wavelet denoising (WD) was employed for a pre-treatment of the direct absorption spectral (DAS) signal to perform a preliminary suppression of high-frequency noise.
View Article and Find Full Text PDFPhotoacoustics
December 2020
A multi-quartz-enhanced photothermal spectroscopy (M-QEPTS) based trace gas detection method is reported for the first time. Different from traditional QEPTS sensor employing a single quartz tuning fork (QTF) as a photothermal detector, two QTFs were used in M-QEPTS to increase the signal amplitude by adding the generated piezoelectric signals. The coating film of the QTFs was removed in order to improve the laser absorption and transmission.
View Article and Find Full Text PDFA quartz-enhanced photoacoustic spectroscopy (QEPAS) gas sensor exploiting a fast and wideband electro-mechanical light modulator was developed. The modulator was designed based on the electro-mechanical effect of a commercial quartz tuning fork (QTF). The laser beam was directed on the edge surface of the QTF prongs.
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