Explorative Data Analysis Methods: Application to Laser-Induced Breakdown Spectroscopy Field Data Measured on the Island of Vulcano, Italy.

One of the strengths of laser-induced breakdown spectroscopy (LIBS) is that a large amount of data can be measured relatively easily in a short time, which makes LIBS interesting in many areas, from geomaterial analysis with portable handheld instruments to applications for the exploration of planetary surfaces. Statistical methods, therefore, play an important role in analyzing the data to detect not only individual compositions but also trends and correlations. In this study, we apply two approaches to explore the LIBS data of geomaterials measured with a handheld device at different locations on the Aeolian island of Vulcano, Italy.

Nitrate and Nitrite Variability at the Seafloor of an Oxygen Minimum Zone Revealed by a Novel Microfluidic In-Situ Chemical Sensor.

Microfluidics, or lab-on-a-chip (LOC) is a promising technology that allows the development of miniaturized chemical sensors. In contrast to the surging interest in biomedical sciences, the utilization of LOC sensors in aquatic sciences is still in infancy but a wider use of such sensors could mitigate the undersampling problem of ocean biogeochemical processes. Here we describe the first underwater test of a novel LOC sensor to obtain in situ calibrated time-series (up to 40 h) of nitrate+nitrite (ΣNOx) and nitrite on the seafloor of the Mauritanian oxygen minimum zone, offshore Western Africa.