Temporal correspondence of selenium and mercury, among brine shrimp and water in Great Salt Lake, Utah, USA.

The specific source of high burdens of selenium (Se) and mercury (Hg) in several bird species at Great Salt Lake (GSL) remain unknown. Frequent co-located water and brine shrimp samples were collected during 2016 through 2017 to identify potential correlations of element concentrations among brines and brine shrimp, a keystone species in the GSL. Like many aquatic systems, GSL is characterized by elevated methylmercury (MeHg) in deep waters.

Total Mercury and Methylmercury Response in Water, Sediment, and Biota to Destratification of the Great Salt Lake, Utah, United States.

Measurements of chemical and physical parameters made before and after sealing of culverts in the railroad causeway spanning the Great Salt Lake in late 2013 documented dramatic alterations in the system in response to the elimination of flow between the Great Salt Lake's north and south arms. The flow of denser, more-saline water through the culverts from the north arm (Gunnison Bay) to the south arm (Gilbert Bay) previously drove the perennial stratification of the south arm and the existence of oxic shallow brine and anoxic deep brine layers. Closure of the causeway culverts occurred concurrently with a multiyear drought that resulted in a decrease in the lake elevation and a concomitant increase in top-down erosion of the upper surface of the deep brine layer by wind-forced mixing.

Maternal transfer of inorganic mercury and methylmercury in aquatic and terrestrial arthropods.

The transfer of mercury from females to their offspring plays an important role in mercury accumulation and toxicity during early development. To quantify the transfer of inorganic mercury and methylmercury from female arthropods to their eggs, the authors collected and analyzed brine shrimp (Artemia franciscana), wolf spiders (Alopecosa spp.), and their attached eggs from aquatic and terrestrial ecosystems at the Great Salt Lake, Utah, USA.

The tropical African mercury anomaly: lower than expected mercury concentrations in fish and human hair.

Mercury is a neurotoxin and global pollutant, and wetlands and newly flooded areas are known to be sites of enhanced production of monomethylmercury, the form of mercury that is readily biomagnified in aquatic food chains to potentially toxic levels. The Okavango Delta in Botswana, Southern Africa, is the largest inland delta in the world and a wetland ecosystem that experiences dramatic annual flooding of large tracts of seasonal floodplains. The Delta was, therefore, expected to be home to high mercury levels in fish and to be an area where local subsistence fishing communities would be at substantial risk of mercury toxicity from fish consumption.

Stability of dimethyl mercury in seawater and its conversion to monomethyl mercury.

Dimethyl mercury (DMHg) is commonly detected in the world's oceans, but little is known about the mechanisms responsible for DMHg degradation in natural waters or the products of this degradation. Similarly, the potential for the conversion of DMHg to monomethyl mercury (MMHg) under the acidic conditions commonly used to preserve samples for MMHg analysis has not been fully addressed. We provide evidence suggesting that DMHg in natural seawater is not readily photodegraded by sunlight as previously thought.

Mercury concentrations and loads in a large river system tributary to San Francisco Bay, California, U.S.A.

In order to estimate total mercury (HgT) loads entering San Francisco Bay, U.S.A.

Dimethylmercury in coastal upwelling waters, Monterey Bay, California.

Depth profiles of dimethylmercury (DMHg) concentration were determined at nearshore to offshore sites in Monterey Bay, California. The onset of spring upwelling in the bay was accompanied by increases in DMHg concentrations. Profiles show DMHg increasing gradually with depth in fall and winter from <0.

Mercury in the San Francisco Estuary.

This review presents some of the published and other important literature on mercury contamination in San Francisco Estuary. Studies on human consumption of contaminated sportfish and on detecting ecological impacts of this contamination in wetland areas validate concerns regarding mercury's toxicity in this system. Mining, industrial, and environmental uses of mercury have occurred for more than a century, resulting in its large historic and continuing transport to the estuary.

Competing ligand exchange-solid phase extraction method for the determination of the complexation of dissolved inorganic mercury (II) in natural waters.

A method employing dual competitive ligand exchange followed by solid phase extraction (CLE-SPE) for characterizing the complexation of inorganic Hg(II) in natural waters is described. This method employs parallel use of two competing ligands: diethyldithiolcarbamate (DEDC), which forms hydrophobic complexes with Hg(II), and thiosalicylic acid (TSA), which forms hydrophilic complexes with Hg(II). Inorganic mercury complexed by natural and competing ligands are separated based on hydrophobicity using C18 solid phase extraction columns.

Model predictions of metal speciation in freshwaters compared to measurements by in situ techniques.

Measurements of trace metal species in situ in a softwater river, a hardwater lake, and a hardwater stream were compared to the equilibrium distribution of species calculated using two models, WHAM 6, incorporating humic ion binding model VI and visual MINTEQ incorporating NICA-Donnan. Diffusive gradients in thin films (DGT) and voltammetry at a gel integrated microelectrode (GIME) were used to estimate dynamic species that are both labile and mobile. The Donnan membrane technique (DMT) and hollow fiber permeation liquid membrane (HFPLM) were used to measure free ion activities.

Comparison of analytical techniques for dynamic trace metal speciation in natural freshwaters.

Several techniques for speciation analysis of Cu, Zn, Cd, Pb, and Ni are used in freshwater systems and compared with respect to their performance and to the metal species detected. The analytical techniques comprise the following: (i) diffusion gradients in thin-film gels (DGT); (ii) gel integrated microelectrodes combined to voltammetric in situ profiling system (GIME-VIP); (iii) stripping chronopotentiometry (SCP); (iv) flow-through and hollow fiber permeation liquid membranes (FTPLM and HFPLM); (v) Donnan membrane technique (DMT); (vi) competitive ligand-exchange/stripping voltammetry (CLE-SV). All methods could be used both under hardwater and under softwater conditions, although in some cases problems with detection limits were encountered at the low total concentrations.