Effect of Temperature on Intermediate Phases of NaV(PO) during Cycling by X-ray Diffraction.

NaV(PO) (NVP) has gained a lot of attention due to its remarkable properties, such as its robust crystal structure, cycle life, rate capabilities, and so on. Nevertheless, NVP undergoes a substantial decrease in its rate capability at low temperatures, which limits its practical applications. In this study, the performance of NVP at low, room, and high temperatures during cycling is thoroughly investigated using synchrotron X-ray diffraction.

Coupling Liquid Electrochemical TEM and Mass-Spectrometry to Investigate Electrochemical Reactions Occurring in a Na-Ion Battery Anode.

A novel approach for investigating the formation of solid electrolyte interphase (SEI) in Na-ion batteries (NIB) through the coupling of in situ liquid electrochemical transmission electron microscopy (ec-TEM) and gas-chromatography mass-spectrometry (GC/MS) is proposed. To optimize this coupling, experiments are conducted on the sodiation of hard carbon materials (HC) using two setups: in situ ec-TEM holder and ex situ setup. Electrolyte (NP30) is intentionally degraded using cyclic voltammetry (CV), and the recovered liquid product is analyzed using GC/MS.