Quantifying order in breath figure patterns through Voronoi entropy.

In this study, we simulate breath figures that are evolving two-dimensional assemblies of droplets on a substrate. We focus on the Voronoi/Shannon entropy of these figures, which quantifies the order related to the coordination number of droplets. We show that the Voronoi entropy of the complete breath figure pattern converges to a value that is the one of a randomly distributed point system.

Impact of composite soft-rigid elastic projectiles: A numerical study.

We study by numerical simulation the impact of a one-dimensional composite projectile, composed of two superposed homogeneous parts, on an infinitely rigid and massive wall. The coefficient of restitution and the contact time are systematically measured as functions of the contrasts of mass and stiffness between the two parts. For purely elastic parts, these quantities show complex trends associated with different dynamics of the deformation waves propagating inside the projectile.

Atomistic Description of Interdroplet Ice-Bridge Formation during Condensation Frosting.

The propagation of frost in an assembly of supercooled dew droplets takes place by the formation of ice protrusions that bridge ice particles and still-liquid droplets. In this work, we develop a Kinetic Monte Carlo (KMC) model to study the formation kinetics of the ice protrusions. The KMC simulations reproduce well the experimental results reported in the literature.

Use of compliant actuators for throwing rigid projectiles.

Muscles and tendons, actuators in robotics, and various sports implements are examples that exploit elasticity to accelerate objects. Tuning the mechanical properties of elastic elements connecting objects can greatly enhance the transfer of mechanical energy between the objects. Here, we study experimentally the throw of rigid projectiles by an actuator, which has a soft elastic element added to the distal end.

Impact dynamics of composite elastorigid projectiles onto solid surfaces.

We investigate the impact of composite objects. They consist of a soft layer on top of a rigid part with a hemispherical impacting end. The coefficient of restitution (e) of such objects is studied systematically as a function of the mass ratio and of the nature of the materials.

Cavitation Mean Expectation Time in a Stretched Lennard-Jones Fluid under Confinement.

We investigate the nucleation of cavitation bubbles in a confined Lennard-Jones fluid subjected to negative pressures in a cubic enclosure. We perform molecular dynamics (MD) simulations with tunable interatomic potentials that enable us to control the wettability of solid walls by the liquid, that is, its contact angle. For a given temperature and pressure, as the solid is taken more hydrophobic, we put in evidence, an increase in nucleation probability.

Ferrofluid Leidenfrost droplets.

We experimentally investigate the behavior of ferrofluid Leidenfrost droplets subject to a static magnetic field gradient. The droplets are deposited on a hot substrate and trapped over the vertical axis of a permanent magnet placed at a distance d above the substrate. Several effects are observed.

Dynamic Wetting Properties of Mesh Substrates with Tunable Water Adhesion.

In nature, wetting phenomena are present nearly everywhere and are a source of inspiration for liquid transportation. A good understanding of the underlying dynamic phenomena that governs wettability is therefore extremely important for researchers involved in bio-inspired surfaces. Herein, we study the adhesive behavior with water of mesh substrates modified with structured copolymers in order to tune the surfaces from parahydrophobic states (high water adhesion) to superhydrophobic states (low water adhesion).

Experimental Characterization of Droplet Adhesion: The Ejection Test Method (ETM) Applied to Surfaces with Various Hydrophobicity.

We study the wetting and the adhesive behavior of substrates made by electropolymerization of copolymers of pyrene substituted with fluoroalkyl and adamantyl groups. The hydrophobicity and water adhesion properties can be tuned by the molar percentage (mol %) of each pyrene monomer so that the substrate properties can vary from superhydrophobic to parahydrophobic, with respectively low and high water adhesion. The ejection test method (ETM) is proposed as an original tool to discriminate and characterize such substrates.

Superpropulsion of Droplets and Soft Elastic Solids.

We investigate the behavior of droplets and soft elastic objects propelled with a catapult. Experiments show that the ejection velocity depends on both the projectile deformation and the catapult acceleration dynamics. With a subtle matching given by a peculiar value of the projectile/catapult frequency ratio, a 250% kinetic energy gain is obtained as compared to the propulsion of a rigid projectile with the same engine.

Room temperature water Leidenfrost droplets.

We experimentally investigate the Leidenfrost effect at pressures ranging from 1 to 0.05 atmospheric pressure. As a direct consequence of the Clausius–Clapeyron phase diagram of water, the droplet temperature can be at ambient temperature in a non-sophisticated lab environment.

Stability of the hydrophilic and superhydrophobic properties of oxygen plasma-treated poly(tetrafluoroethylene) surfaces.

Poly(tetrafluoroethylene) (PTFE) materials were exposed to low and high-energy oxygen plasma, and the stability of the materials' surface was evaluated using contact angle, surface roughness, and surface chemistry characterizations. Lower-energy oxygen plasma treatments exhibited hydrophilic behavior with contact angles as low as 87°, and the higher-energy oxygen plasma treatments exhibited superhydrophobic behavior with contact angles as high as 151°. The wettability of all the treated samples as stored in air and in water was found to be stable in time as evidenced by the statistically insignificant differences in the advancing, receding, and hysteresis contact angles.

Jet impact on a soap film.

We experimentally investigate the impact of a liquid jet on a soap film. We observe that the jet never breaks the film and that two qualitatively different steady regimes may occur. The first one is a refractionlike behavior obtained at small incidence angles when the jet crosses the film and is deflected by the film-jet interaction.

Take off of small Leidenfrost droplets.

We put in evidence the unexpected behavior of Leidenfrost droplets at the later stage of their evaporation. We predict and observe that, below a critical size Rl, the droplets spontaneously take off due to the breakdown of the lubrication regime. We establish the theoretical relation between the droplet radius and its elevation.

Ratchetlike motion of a shaken drop.

We study the motion of a drop lying on a plate simultaneously submitted to horizontal and vertical harmonic vibrations. The two driving vibrations are adjusted to the same frequency, and, according to their relative amplitude and phase difference DeltaPhi, the drop experiences a controlled directed motion with a tunable velocity. We present a simple model putting in evidence the underlying mechanism leading to this ratchetlike motion of the drop.

Cosine law at the atomic scale: toward realistic simulations of Knudsen diffusion.

We propose to reconsider the diffusion of atoms in the Knudsen regime in terms of a complex dynamical reflection process. By means of molecular dynamics simulations, we emphasize the asymptotic nature of the cosine law of reflection at the atomic scale, and carefully analyze the resulting strong correlations in the reflection events. A dynamical interpretation of the accommodation coefficient associated with the slip at the wall interface is also proposed.

Vibration of submillimeter-size supported droplets.

We study the fundamental vibration mode of supported submillimeter-size droplets. Using an analogy with a simple oscillator we derive a semianalytical expression for the eigenfrequency and the scaling law of the energy dissipation within the droplet. The experimental results obtained for mercury drops deposited on glass are compared with the model.

Stretching an adsorbed polymer globule.

Using molecular dynamic simulation, we study the stretching of an adsorbed homopolymer in a poor solvent with one end held at a distance ze from the substrate. We measure the vertical force f on the end of the chain as a function of the extension ze and the substrate interaction energy w. The force reaches a plateau value at large extensions.

Phase-field approach for faceted solidification.

We extend the phase-field approach to model the solidification of faceted materials. Our approach consists of using an approximate gamma plot with rounded cusps that can approach arbitrarily closely the true gamma plot with sharp cusps that correspond to faceted orientations. The phase-field equations are solved in the thin-interface limit with local equilibrium at the solid-liquid interface [A.

Measuring kinetic coefficients by molecular dynamics simulation of zone melting.

Molecular dynamics simulations are performed to measure the kinetic coefficient at the solid-liquid interface in pure gold. Results are obtained for the (111), (100), and (110) orientations. Both Au(100) and Au(110) are in reasonable agreement with the law proposed for collision-limited growth.