Chemical Short-Range Order (CSRO) has attracted recent attention from many researchers, creating intense debates about its impact on material properties. The challenges lie in confirming and quantifying CSRO, as its detection proves exceptionally demanding, contributing to conflicting data in the literature regarding its true effects on mechanical properties. Our work uses high-precision calorimetric data to unambiguously prove the existence and, coupled with atomistic simulations, quantify the type of CSRO.
View Article and Find Full Text PDFInterpreting diffuse intensities in electron diffraction patterns can be challenging in samples with high atomic-level complexity, as often is the case with multi-principal element alloys. For example, diffuse intensities in electron diffraction patterns from simple face-centred cubic (fcc) and related alloys have been attributed to short-range order, medium-range order or a variety of different {111} planar defects, including thin twins, thin hexagonal close-packed layers, relrod spiking and incomplete ABC stacking. Here we demonstrate that many of these diffuse intensities, including [Formula: see text]{422} and [Formula: see text]{311} in ⟨111⟩ and ⟨112⟩ selected area diffraction patterns, respectively, are due to reflections from higher-order Laue zones.
View Article and Find Full Text PDFRuddlesden-Popper (layered perovskite) phases are attracting significant interest because of their unique potential for many applications requiring mixed ionic and electronic conductivity. Here we report a new, previously undiscovered layered perovskite of composition, Ce SrMnO ( x = 0.1, 0.
View Article and Find Full Text PDFHigh Entropy Alloys (HEAs) are new classes of structural metallic materials that show remarkable property combinations. Yet, often times interesting compositions are still found by trial and error. Here we show an "Effective Atomic Radii for Strength" (EARS) methodology, together with different semi-empirical and first-principle models, can be used to predict the extent of solid solution strengthening to discover and design new HEAs with unprecedented properties.
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