Comparative electrochemical and impedance studies of self-assembled rigid-rod molecular wires and alkanethiols on gold substrates.

A study of the charge transfer and self-assembly characteristics of two new rigid-rod molecular wires 1 and 2 assembled on polycrystalline gold electrodes was carried out using electrochemical impedance spectroscopy and cyclic voltammetry. This class of wires have precisely controlled (ca. 1.

Towards multifunctional microelectrode arrays.

A single microelectrode array platform, divided into groups of microelectrodes with flexible multiplexing can enable a 'defective' cluster of microelectrodes to be readily identified, by comparing normalised currents with the numbers of microelectrodes in the groups of arrays. This generic design principle may be extended for integrating multiple analyte sensing in a single microarray platform. The calibration of the microelectrode arrays, using white light interferometry and electrochemistry is described.