Publications by authors named "Francesca Romana Lamastra"

Article Synopsis
  • Two types of porous supporting materials were developed using chemical vapor deposition: CNT-decorated diatomite (CNT/DE) and CNT sponges (CNS) for creating form-stable phase-change material (PCM) composites with polyethylene glycol (PEG).
  • The CNT/DE matrix featured well-entangled nanotubes and enabled high PEG loading (75 wt%) without leakage, while the CNS formed a 3D porous structure that also supported high PEG incorporation.
  • Both PCM composites exhibited excellent thermal reliability through numerous melting-solidification cycles and demonstrated reduced cooling power requirements in building applications, indicating their potential for effective thermal energy storage in building materials.
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Due to global environmental concerns related to climate change, the need to improve the service life of structures and infrastructures is imminently urgent. Structural elements typically suffer service life reductions, leading to poor environmental sustainability and high maintenance costs. Graphene oxide nanosheets (GONSs) effectively dispersed in a cement matrix can promote hydration, refine the microstructure and improve interfacial bonding, leading to enhanced building materials' performance, including mechanical strength and transport properties.

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The impact of extra-low dosage (0.01% by weight of cement) Graphene Oxide (GO) on the properties of fresh and hardened nanocomposites was assessed. The use of a minimum amount of 2-D nanofiller would minimize costs and sustainability issues, therefore encouraging the market uptake of nanoengineered cement-based materials.

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A native isolate of the colonial benthic diatom Staurosirella pinnata was cultivated for biosilica production. The silicified cell walls (frustules) were used as a source of homogeneous and structurally predictable porous biosilica for dye trapping and random laser applications. This was coupled with the extraction of lipids from biomass showing potential to fabricate photoactive composite materials sustainably.

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Undoped and Europium-doped titania nanofibers have been fabricated by electrospinning technique, using a single multielement Titanium/Europium source. In this communication we present the synthesis, structural and spectroscopic characterisation of Eu-doped TiO2 nanofibers starting from polyvinylpyrrolidone, titanium tetraisopropoxide (Ti(OiPr)4) and Eu(hfa)3 x diglyme (Hhfa = 1,1,1,5,5,5-hexafluoroacetyacetone, diglyme = CH3O(CH2CH2O)2CH3). The chosen system allowed to investigate a wide compositional range, i.

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