Coherent Ultrafast Stimulated X-Ray Raman Spectroscopy of Dissipative Conical Intersections.

The quantum coherent dynamics of a vibronic wave packet in a molecule passing through a conical intersection can be revealed using attosecond transient coherent Raman spectroscopy. In particular, the time evolution of the electronic coherence can be monitored in the presence of vibrational dynamics. So far, the technique has been investigated without including environmental quantum noise.

Hidden Phase of the Spin-Boson Model.

A quantum two-level system immersed in a sub-Ohmic bath experiences enhanced low-frequency quantum statistical fluctuations which render the nonequilibrium quantum dynamics highly non-Markovian. Upon using the numerically exact time-evolving matrix product operator approach, we investigate the phase diagram of the polarization dynamics. In addition to the known phases of damped coherent oscillatory dynamics and overdamped decay, we identify a new third region in the phase diagram for strong coupling showing an aperiodic behavior.