Publications by authors named "Florian Brown-Altvater"
Article Synopsis
- Diamine-appended Mg(dobpdc) frameworks show strong potential for CO capture but their stability against SO, a component in industrial exhaust, needed testing.
- Experiments reveal that dmpn-Mg(dobpdc) retains 91% of CO capture capacity even when exposed to humid flue gas with SO, indicating robust performance under realistic conditions.
- The study also finds that 1°,1° diamines like dmpn are more stable in the presence of humid SO than 1°,2° or 1°,3° variants, offering insights for optimizing CO capture materials.
The characterization of specific phonon modes and exciton states that lead to efficient singlet fission (SF) may be instrumental in the design of the next generation of high-efficiency photovoltaic devices. To this end, we analyze the absolute resonance Raman (RR) cross sections for tetracene (Tc) both as a monomer in solution and as a crystalline solid in an aqueous suspension of nanocrystals. For both systems, a time-dependent wavepacket model is developed that is consistent with the absolute RR cross sections, the magnitude of the absorption cross sections, and the vibronic line shapes of the fluorescence.
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